Question

In: Chemistry

Determine the pH of the following solutions. (a) a 0.48 M CH3COOH solution (b) a solution...

Determine the pH of the following solutions.

(a) a 0.48 M CH3COOH solution


(b) a solution that is 0.48 M CH3COOH and 0.22 M CH3COONa

Solutions

Expert Solution

a.                   CH3COOH -----------------> CH3COO^- (aq) + H^+ (aq)

               I      0.48                                        0                         0

              C       -x                                           +x                         +x

              E     0.48-x                                       +x                        +x

                           ka   = [CH3COO^-][H^+]/[CH3COOH]

                          1.8*10^-5   = x*x/0.48-x

                         1.8*10^-5*(0.48-x) = x^2

                               x   = 0.00293

                          [H^+]   = x   = 0.00293M

                          PH    =   -log[H^+]

                                  =   -log0.00293

                                  = 2.5331

b. [CH3COOH]   = 0.48M

     [CH3COONa] = 0.22M

      PH   = Pka + log[CH3COONa]/[CH3COOH}

             = 4.75 + log0.22/0.48

             = 4.75-0.3388

             = 4.4112 >>>answer


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