A 0.4569 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid....

A 0.4569 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2·4H2O and removed by filtration. The resulting filtrate and washings were diluted to a total volume of 250.0 mL. A 20.00 mL aliquot of this solution was buffered, and titration of the lead, copper, and zinc in solution required 34.02 mL of 0.001513 M EDTA. Thiosulfate was used to mask the copper in a second 25.00 mL aliquot. Titration of the lead and zinc in this aliquot required 34.42 mL of the EDTA solution. Finally, cyanide was used to mask the copper and the zinc in a third 30.00 mL aliquot. Titration of the lead in this aliquot required 25.92 mL of the EDTA solution. Determine the percent composition by mass of each metal in the pewter sample.

Expert Solution

queen_honey_blossom answered 1 year ago

A 0.4423 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid....

A 0.4423 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2·4H2O and removed by filtration. The resulting filtrate and washings were diluted to a total volume of 200.0 mL. A 15.00 mL aliquot of this solution was buffered, and titration of the lead, copper, and zinc in solution required 35.87 mL of 0.001481 M EDTA. Thiosulfate was used to mask the copper in a second 20.00 mL aliquot. Titration of...

A 0.4640 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid....

A 0.4640 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2·4H2O and removed by filtration. The resulting filtrate and washings were diluted to a total volume of 200.0 mL. A 15.00 mL aliquot of this solution was buffered, and titration of the lead, copper, and zinc in solution required 34.88 mL of 0.001523 M EDTA. Thiosulfate was used to mask the copper in a second 20.00 mL aliquot. Titration of...

A 0.4809 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid....

A 0.4809 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2·4H2O and removed by filtration. The resulting filtrate and washings were diluted to a total volume of 200.0 mL. A 20.00 mL aliquot of this solution was buffered, and titration of the lead, copper, and zinc in solution required 34.79 mL of 0.001492 M EDTA. Thiosulfate was used to mask the copper in a second 25.00 mL aliquot. Titration of...

A 0.4775 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid....

A 0.4775 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2·4H2O and removed by filtration. The resulting filtrate and washings were diluted to a total volume of 200.0 mL. A 20.00 mL aliquot of this solution was buffered, and titration of the lead, copper, and zinc in solution required 35.98 mL of 0.001455 M EDTA. Thiosulfate was used to mask the copper in a second 25.00 mL aliquot. Titration of...

A 0.4713 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid....

A 0.4713 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO2·4H2O and removed by filtration. The resulting filtrate and washings were diluted to a total volume of 250.0 mL. A 15.00 mL aliquot of this solution was buffered, and titration of the lead, copper, and zinc in solution required 35.63 mL of 0.001504 M EDTA. Thiosulfate was used to mask the copper in a second 20.00 mL aliquot. Titration of...

A 0.4592 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid....

A 0.4592 g sample of pewter, containing tin, lead, copper, and zinc, was dissolved in acid. Tin was precipitated as SnO 2 ⋅ 4 H 2 O and removed by filtration. The resulting filtrate and washings were diluted to a total volume of 200.0 mL. A 15.00 mL aliquot of this solution was buffered, and titration of the lead, copper, and zinc in solution required 34.07 mL of 0.001476 M EDTA . Thiosulfate was used to mask the copper in...

A 0.4672 g sample of pewter (containing tin, lead, copper, and zinc) was dissolved in acid....

A 0.4672 g sample of pewter (containing tin, lead, copper, and zinc) was dissolved in acid. The precipitate SnO2

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For an alloy that consists of 74.9 g copper, 108.0 g zinc, and 7.3 g lead, what are the concentrations of (a) Cu, (b) Zn, and (c) Pb in weight percent? The atomic weights of Cu, Zn, and Pb are 63.54, 65.39, and 207.2 g/mol, respectively.

A sample of a chromium-containing alloy weighing 3.450 g was dissolved in acid, and all the...

A sample of a chromium-containing alloy weighing 3.450 g was dissolved in acid, and all the chromium in the sample was oxidized to 2CrO42–. It was then found that 3.18 g of Na2SO3 was required to reduce the 2CrO42– to CrO2– in a basic solution, with the SO32– being oxidized to SO42–. Write a balanced equation for the reaction of 2CrO42– with SO32- in a basic solution. How many grams of chromium were in the alloy sample? What was the...

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