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Why was Cu prepared from a pure metal? Why was Ca prepared from a salt? Why...

Why was Cu prepared from a pure metal? Why was Ca prepared from a salt? Why is CaCO3 a better salt for this purpose than CaCl2?

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Gun metal is (a) Cu + Zn (b) Cu + Sn + Zn (c) Cu + Sn (d) Zn + Sn
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