Question

In: Chemistry

Cu3Au undergoes a phase transition. At elevated temperatures, it has the structure of Cu, where each...

Cu3Au undergoes a phase transition. At elevated temperatures, it has the structure of Cu, where each position is filled randomly with Cu or gold atoms (i.e. at each position, there is a 1/4 probability that the atom is Au, and a 3/4 probability that the atom is Cu). At lower temperatures, the thermodynamically stable phase is a cubic one with space group Pm3m (#221), with a= 3.74Å. Cu is at (0, 0.5, 0.5) and Au is at (0,0,0).

a.Show unit cells of the ordered version.
b.Compare this structure to that of Cu.
c.Explain why the disordered version is favored at higher temperatures

Solutions

Expert Solution


Related Solutions

A) A system of proteins undergoes a phase transition. Which of the following quantities would you...
A) A system of proteins undergoes a phase transition. Which of the following quantities would you expect to change the most significantly? The total number of particles in the system, The density of the system, The total mass of the system, or These will all not change B) A flow of liquid has a Reynold's number of 1 million. Which of the following statements would best describe this flow? Flow that moves from high to low, Flow that moves for...
descripe the crystal structure kaolinite? with drawong, and where is hhe final crystalline phase in firred...
descripe the crystal structure kaolinite? with drawong, and where is hhe final crystalline phase in firred Kaolinite?
In python this structure can be represented by a set of tuples, where each tuple has...
In python this structure can be represented by a set of tuples, where each tuple has two elements. The following two lines would build the set given above and the print it. >>> L = [(’dog’,’white’), (’cat’,’black’),(’mouse’,’black’)] >>> f = set(L) >>> print(f) {(’cat’, ’black’), (’dog’, ’white’), (’mouse’, ’black’)} In the example, first we store the tuples into a list, and then we create a set with those tuples. There are obviously countless other ways to initialize f and get...
Describe the 4 phases of demographic transition.  2 part question For each phase, compare crude birth...
Describe the 4 phases of demographic transition.  2 part question For each phase, compare crude birth rates (CBR) to crude death rates (CDR), and state whether the population is stable, growing, or declining in each.  Explain factors that contribute to changes in CBR and CDR between phases.
Iron has an fcc structure at temperatures higher than 913 degree centigrade, and bcc structure below...
Iron has an fcc structure at temperatures higher than 913 degree centigrade, and bcc structure below this temperature. At 1148 oC, iron can dissolve maximum of 2.08% of carbon to form steel. However, at temperature lower than 723 oC, iron can only dissolve maximum 0.025% carbon. The atomic radius is 0.129 nm in both structures (don't consider thermal expansion). One of the largest void is located at (0, ½ , 0) for fcc. What is the largest void size in...
Iron has an fcc structure at temperatures higher than 913 degree centigrade, and bcc structure below...
Iron has an fcc structure at temperatures higher than 913 degree centigrade, and bcc structure below this temperature. At 1148 oC, iron can dissolve maximum of 2.08% of carbon to form steel. However, at temperature lower than 723 oC, iron can only dissolve maximum 0.025% carbon. The atomic radius is 0.129 nm in both structures (don't consider thermal expansion). One of the largest void is located at (0, ½ , 0) for fcc. What is the largest void size in...
A voltaic cell consists of Cu²⁺/Cu and Cd²⁺/Cd half-cells. Each compartment has a volume of 0.500...
A voltaic cell consists of Cu²⁺/Cu and Cd²⁺/Cd half-cells. Each compartment has a volume of 0.500 L with the following initial concentrations: [Cu²⁺] = 1.250 M; [Cd²⁺] = 0.250 M at 25°C. What is the [Cu²⁺] when the voltage has dropped to 0.719 V? (E⁰ for Cu²⁺/Cu = 0.340 V and E⁰ for Cd²⁺/Cd = -0.400 V.)
Determine the Lewis structure of each of the following molecules. Include formal charges, where appropriate: (a)...
Determine the Lewis structure of each of the following molecules. Include formal charges, where appropriate: (a) PBr3 (b) SiF4 (c) BF4¯
Explain the terms, Price Taker and Price Seeker. For each case, identify a market structure where...
Explain the terms, Price Taker and Price Seeker. For each case, identify a market structure where we are likely to observe the behavior. 150 words
describe the structure of hemoglobin. how many oxygen molecules does each hemoglobin carry? where are senescent...
describe the structure of hemoglobin. how many oxygen molecules does each hemoglobin carry? where are senescent blood cells and hemoglobin broken down? what are the breakdown products of hemoglobin? how can the excessive breakdown of RBC's cause jaundice?
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT