Question

In: Chemistry

1) A buffer is prepared by mixing 152 mL of 0.452 M HCl and 0.495 L...

1) A buffer is prepared by mixing 152 mL of 0.452 M HCl and 0.495 L of 0.400 M sodium acetate.

a. What is the pH?

b. How many grams of KOH must be added to 0.500 L of the buffer to change the pH by 0.18 units?

2) A buffer is prepared by mixing 52.6 mL of 0.050 M sodium bicarbonate and 10.0 mL of 0.10 M NaOH.

a. What is the pH?

b. How many grams of HCl must be added to 25.0 mL of the buffer to change the pH by 0.07 units?

Solutions

Expert Solution

1 a)

Number of mmol of HCl

Number of mmol of sodium acetate

b)

0.5 L of buffer contains mmoles of acetic acid and mmol of sodium acetate. Let W mmol of KOH is added.

53-W mmol of acetic acid will remain uneutralised. 99.9+W mmol of acetate salt will be formed.

mmol

The molar mass of KOH is 56.11 g/mol

The mass of KOH


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