In: Chemistry
A thermometer having 1st order dynamics with a time constant of 1min is placed in a temperature bath at 50oC. After the thermometer reaches steady state, it is suddenly placed in a bath at 60oC at t = 0 and left there for 1 min, after which it is immediately returned to the bath at 50 oC. a. Draw a sketch showing the variation of the thermometer reading with time. b. Calculate the thermometer reading at t = 0.5 min and at t = 2.0 min.
The equation for the first order dynamics is as follows
tau = time constant = 1min
T1 = final temperature = 60oC
T = temperature at any time t
also, To = initial temperature = 50oC
upon solving the differential, we can derive the integrated law as shown,
The graph declines again towards original value because after 1 min the set-up is again reversed.
For calculating the thermometer readings at different times, simply substitute the values.
For instance at t = 0.5 min
T = 60 - (60 - 50)(e-0.5)
= 53.94 (or)
= 54oC (approximately)
For t = 2min we first need to find the value at t = 1min as that will become our new To and 50oC is our new T1 for time beyond 1min
T(at t=1min) = 60 - (60 - 50)(e-1) = 56.32oC
Now for t=2min, the equation becomes,
substitute t = 2min
we get, T = 52.32oC