Question

In: Chemistry

A thermometer having 1st order dynamics with a time constant of 1min is placed in a...

A thermometer having 1st order dynamics with a time constant of 1min is placed in a temperature bath at 50oC. After the thermometer reaches steady state, it is suddenly placed in a bath at 60oC at t = 0 and left there for 1 min, after which it is immediately returned to the bath at 50 oC. a. Draw a sketch showing the variation of the thermometer reading with time. b. Calculate the thermometer reading at t = 0.5 min and at t = 2.0 min.

Solutions

Expert Solution

The equation for the first order dynamics is as follows

tau = time constant = 1min

T1 = final temperature = 60oC

T = temperature at any time t

also, To = initial temperature = 50oC

upon solving the differential, we can derive the integrated law as shown,

The graph declines again towards original value because after 1 min the set-up is again reversed.

For calculating the thermometer readings at different times, simply substitute the values.

For instance at t = 0.5 min

T = 60 - (60 - 50)(e-0.5)

= 53.94 (or)

= 54oC (approximately)

For t = 2min we first need to find the value at t = 1min as that will become our new To and 50oC is our new T1 for time beyond 1min

T(at t=1min) = 60 - (60 - 50)(e-1) = 56.32oC

Now for t=2min, the equation becomes,

substitute t = 2min

we get, T = 52.32oC


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