Question

In: Chemistry

1. Rank the following element from the least electronegative (1) to most electronegative (6) Si Ca...

1. Rank the following element from the least electronegative (1) to most electronegative (6)
Si
Ca
P
Ba
F
N

2. A chemical bond between which of the following elements whold be considered nonpolor covalent? (select all the apply.)
A) H-C
B) C-O
C) Be-Cl
D) C-S
E) F-Cl
F) H-N
G) K-Cl
H) Si-P
I) Mn-O
J) B-N

Solutions

Expert Solution


electronegativity decreases down in a group : Ba < Ca , ,, P <N same group members
electronegativity increases from left to right in a period Si < P ,,,, N < F
Since Ba is below Ca in 2nd group , Ba has least value
Si and P are in same period So Si has less value than P
All can be solved using periodic table

Hence answer : Ranking elements in the increasing order of electro negativity
as
Ba < Ca < Si < P < N < F

Ba :1

Ca :2

Si :3

P;4

N:5

F;6


METAL AND NON METAL BONDS ARE IONIC .Hence they will be purely
ionic.
let us find out electronegativity difference between atoms
in covalent bond . When the difference is small, the compound
will be covalent
A) H-C
DIFFERENCE in electronegativity
dE.N = 2.56 -2.26 = 0.3


B) C-O
dE.N = 3.44-2.55 = 0.89 : polar


C) Be-Cl
dE.N = 3.16 -1.57 = 1.59 ;polar

D) C-S
dE.N = 2.58 -2.56 = 0.02 ; nonpolar

E) F-Cl
dEN = 3.96 - 3.16 = 0.8 : polar


F) H-N
dEN = 3.04 -2.20 =0.84 : polar

  
G) K-Cl = ionic


H) Si-P =
dEN = 2.19-1.90 = 0.29

I) Mn-O= ionic bond

J) B-N =

dEN = 3.04 - 2.04 =1 : polar

dE.N value smaller than 0.5 considered as covalent

hence answer is

A)C-H and

D) C-S
***************
Thank you


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