Question

In: Chemistry

42. You can prove in the following way that it is overall more efficient for an...

42. You can prove in the following way that it is overall more efficient for an
engine to exhaust at the ambient environmental temperature than to exhaust
at a cooler temperature that requires refrigeration. Suppose that the hot
reservoir is at Th, the ambient temperature is Ta, and the refrigerated tem-
perature is Tc. The engine cannot put out more work than would a Carnot
engine operating between Th and Tc, so Weng = eQh = a[(Th − Tc)/Th] Qh,
where a ≤ 1. Likewise the refrigerator cannot require less work input than
a Carnot refrigerator, so Wfrig = bQa[(Ta − Tc)/Ta], where b ≥ 1. The net
work output is that from the engine minus that needed to run the refrigerator,
Wnet = Weng − Wfrig. Show that this quantity is less than the work you would
get out of the engine if it simply ran between Th and Ta without any refrig-
eration, which would be Weng = aQh[(Th − Ta)/Th]. (For the Carnot engine,
Qh/Th = Qa/Ta.)

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