Question

In: Chemistry

once vanillin has reacted with NaOH and NaBH4, why can you only add enough HCl to...

once vanillin has reacted with NaOH and NaBH4, why can you only add enough HCl to make the pH go down to 6? what would occur mechanistically if enough HCl (too much) was added to make the pH go down to 1?

Solutions

Expert Solution

Sodium borohydride or sodium hydroxide solutions are basic in nature. So for these reactions generally basic or nutral pH is recomended. But it can work upto pH=6. Because pH=6 is very mild acedic condition. This slightly acedic medium can help to controll selectivity as well as vigorisity of the reaction by reducing the reactivity of the reagents. But at pH=1, i.e., very strong acedic condition, sodium borohydride fully converted to boric acid and hydrogen and sodium hydroxide converted to sodium chloride and water. So there are no more sodium borohydride or sodium hydroxide present in the solution. So no reaction.

Hence pH > 6 is recomended for this type of reaction.


Related Solutions

If the temperature is too high when NaBH4 is added to already reacted NaOH and Vanillin,...
If the temperature is too high when NaBH4 is added to already reacted NaOH and Vanillin, what is the mechanism of the decomposition of NaBH4? does NaBH4 become more reactive with H2O instead of the carbonyl group on vanillin which would instead produce NaBO2 and Hydrogen gas?
If you add 35.6mL of 5.20M Hcl to 35.6mL of 7.40M NaOH, the solution that you...
If you add 35.6mL of 5.20M Hcl to 35.6mL of 7.40M NaOH, the solution that you generate is what percent NaCl? (Keep in mind the following... you must balance the equation to ge the answer and you must also consider what is the final volume of this solution?)(molar mass of NaCl is 58.44g/mol)
Assuming you use 2.5 g vanillin and 5.0 mL of a 3.42 M NaBH4 solution, what...
Assuming you use 2.5 g vanillin and 5.0 mL of a 3.42 M NaBH4 solution, what is the theoretical yield of vanillyl alcohol in moles? in grams?
How would your experimental mass of NaCl change if you did not add enough HCL for...
How would your experimental mass of NaCl change if you did not add enough HCL for all the sodium carbonate to completely react?
You roll 48 dice all at once. If you add up only the even numbers rolled,...
You roll 48 dice all at once. If you add up only the even numbers rolled, what is the chance that the sum will be 104 or more??
Why is the molar heat in a reaction between HCl and NaOH greater than in a...
Why is the molar heat in a reaction between HCl and NaOH greater than in a reaction between HOAc and NaOH
11.       Which of the following statements is CORRECT?             a.         If you add enough...
11.       Which of the following statements is CORRECT?             a.         If you add enough randomly selected stocks to a portfolio, you can completely eliminate all of the market risk from the portfolio.             b.         If you were restricted to investing in publicly traded common stocks, yet you wanted to minimize the riskiness of your portfolio as measured by its beta, then according to the CAPM theory you should invest an equal amount of money in each stock...
Isolation of Nicotine from Tobacco 1. Why did you add 5 mL of 3 M NaOH...
Isolation of Nicotine from Tobacco 1. Why did you add 5 mL of 3 M NaOH to the mixture prior to the steam distillation? 2. How can you tell when steam distillation is complete when a large quantity of an organic compound is steam distilled? 3. Is the nicotine you isolated pure? Provide experimental evidence to support your answer.
1. What percentage (%) is 1.5 M NaOH?ans: 6% 2. If you add 10g of NaOH...
1. What percentage (%) is 1.5 M NaOH?ans: 6% 2. If you add 10g of NaOH to 500 ml, what is the concentration, in percent, of the solution? ans: 2% NaCl solution 3. If you add 10g of NaCl to make a 3 M solution, what is the total volume? mw=58.44 ans: 57 ml NaCl solution 4. Given 30% NaOH solution, how man mL's solution would you use to prepare 300 ml of 10% solution? ans: 100 ml of NaOH
After 2.02 g of Al has reacted completely with 0.4 L of 2.75 M HCl, what...
After 2.02 g of Al has reacted completely with 0.4 L of 2.75 M HCl, what is the molarity of the remaining HCl? 2Al (s) + 6HCl (aq) → 2AlCl3 (aq) + 3H2 (g)
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT