Question

In: Chemistry

consider the following system at equilibrium: SiF4 (g) + 2H2O + heat 《》SiO2 (g) + 4HF...

consider the following system at equilibrium:
SiF4 (g) + 2H2O + heat 《》SiO2 (g) + 4HF (g)

a. Is this reaction endothermic or exothermic?
b Which direction will the equilibrium shift if HF is added?
c. Which direction will the equilibrium shift if H20 is removed?
d. Which direction will the equilibrium shift if the system is heated?

Solutions

Expert Solution

From Le Chatelier's principle

1.If there are more moles of reactants, an increase in volume will shift the equilibrium to the left in order to favor the reactants. When there is a decrease in volume, the equilibrium will shift towards the side of the reaction with fewer moles.

2. When there is a decrease in pressure, the equilibrium will shift towards the side of the reaction with more moles of gas.When there is an increase in pressure, the equilibrium will shifttowards the side of the reaction with fewer moles of gas.

3. For an exothermic reaction, if you increase the temperature you are increasing the amount of products, and so you shift the balance at equilibrium back toward reactants.

4. If you add reaction products to a chemical system at equilibrium, you can expect that some amount of product will be converted into reactants, while if you add reactants, some amount of reactants will be converted into products so that equilibrium is maintained.

So answer is


Related Solutions

Consider the following reaction at equilibrium. 2H2O (g) + 2SO2 (g) <--> 2H2S (g) + 3O2...
Consider the following reaction at equilibrium. 2H2O (g) + 2SO2 (g) <--> 2H2S (g) + 3O2 (g) What effect will adding more H2S have on the system? A) The reaction will shift in the direction of reactants B) The equilibrium constant will increase C) The reaction will shift in the direction of products D) The equilibrium constant will decrease E) No change will be observed Can you explain why the one that is the right answer correct and along with...
Consider the following system at equilibrium N2(g)+3H2(g) <------> 2NH3(g)+ heat Indicatre which way the reaction wil...
Consider the following system at equilibrium N2(g)+3H2(g) <------> 2NH3(g)+ heat Indicatre which way the reaction wil shift when making the following changes 1. Decreasing in the temperture 2. Increasing in the temperture 3. Removing some of NH3 4. Removing some of the H2O 5. Adding some O2 6. Removing some N2 ****Pick from these answers **** A. Forward reaction will increase B. Reverse reaction will increase C. There will be no change in either direction
Part A - At 100oC, The equilibrium constant for the reaction: CF4(g) + 2H2O(g) ⇌CO2(g) +...
Part A - At 100oC, The equilibrium constant for the reaction: CF4(g) + 2H2O(g) ⇌CO2(g) + 4HF(g)    is   Kc,1 = 5.9 And the equilibrium constant at 100oC for the reaction: CO(g) + ½ O2(g) ⇌ CO2(g)                      is   Kc,2 = 1.3 Compute the equilibrium constant at 100oC for the reaction (2 sig figs) 2 CF4(g) + 4H2O(g) ⇌2CO(g) + 8HF(g) + O2(g)          is Kc,3 = ? Part B - Consider the reaction below (Equilibrium Constant @ 300K = Kp = 0.150)...
23) Consider the following system at equilibrium. 2CO(g) + O2(g) <----> 2CO2(g) a) How will increasing...
23) Consider the following system at equilibrium. 2CO(g) + O2(g) <----> 2CO2(g) a) How will increasing the concentration of CO shift the equilibrium? To the right To the left No effect b) How will increasing the concentration of CO2 shift the equilibrium? To the right To the left No effect c) How will decreasing the the volume of the container shift the equilibrium? To the right To the left No effect
Consider the following equilibrium system: COCl2(g) <----> CO(g) + Cl2(g) A 10.00 L evacuated flask is...
Consider the following equilibrium system: COCl2(g) <----> CO(g) + Cl2(g) A 10.00 L evacuated flask is filled with 0.4121 mol COCl2(g) at 297.9 K. The temperature is then raised to 606.9 K, where the decomposition of COCl2 gas takes place to an appreciable extent. When equilibrium is established, the total pressure in the flask is 3.000 atm. What is the value of the equilbrium constant in terms of concentrations, Kc, at 606.9 K? Kc =_______
Consider the following system at equilibrium. S(s)+O2(g)<--->SO2(g) 1. How will adding more S(s) shift the equilibrium?...
Consider the following system at equilibrium. S(s)+O2(g)<--->SO2(g) 1. How will adding more S(s) shift the equilibrium? A) to the right B) to the left C) no effect 2. How will removing some SO2(g) shift the equilibrium? A) to the right B) to the left C) no effect 3. How will decreasing the volume of the container shift the equilibrium? A) to the right B) to the left C) no effect
Consider the following system at equilibrium. 2CO(g)+O2(g)<--->2CO2(g) 1. How will increasing the concentration of CO shift...
Consider the following system at equilibrium. 2CO(g)+O2(g)<--->2CO2(g) 1. How will increasing the concentration of CO shift the equilibrium? A) to the right B) to the left C) no effect 2. How will increasing the concentration of CO2 shift the equilibrium? A) to the right B) to the left C) no effect 3. How will decreasing the the volume of the container shift the equilibrium? A) to the right B) to the left C) no effect
Consider the following equilibrium: 2NOBr(g) <------> 2NO(g) + Br2(g). An equilibrium mixture is 0.146 M NOBr,...
Consider the following equilibrium: 2NOBr(g) <------> 2NO(g) + Br2(g). An equilibrium mixture is 0.146 M NOBr, 0.270 M NO, and 0.236 M Br2. a) What is the value of Kc at the temperature of the above concentrations? b) How many moles/liter of NOBr must be added to the above equilibrium mixture to produce an equilibrium mixture that is 0.439 M Br2? c) If the temperature is 370 K, what is the value of Kp? d) What is the value of...
Consider the reaction at 298 K SO2(g) + 2H2S(g) ? 3S(s) + 2H2O (g) The ?G
Consider the reaction at 298 K SO2(g) + 2H2S(g) ? 3S(s) + 2H2O (g) The ?G
23.Consider the following equilibrium process at 686°C: CO2(g) + H2(g) ⇌ CO(g) + H2O(g) The equilibrium...
23.Consider the following equilibrium process at 686°C: CO2(g) + H2(g) ⇌ CO(g) + H2O(g) The equilibrium concentrations of the reacting species are [CO] = 0.0580 M, [H2] = 0.0430 M, [CO2] = 0.0900 M, and [H2O] = 0.0420 M. (a) Calculate Kc for the reaction at 686°C. ________ (b) If we add CO2 to increase its concentration to 0.460 mol / L, what will the concentrations of all the gases be when equilibrium is reestablished? CO2: M H2: M CO:...
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT