Question

In: Chemistry

Phosphoric acid is a triprotic acid. Calculate the [PO4^3-] if you start out with 5.00 M...

Phosphoric acid is a triprotic acid. Calculate the [PO4^3-] if you start out with 5.00 M phosphoric acid.

Solutions

Expert Solution

Phosphoric acid is triprotic (H3PO4)

Given : [H3PO4] = 5 M

.

1.   ...(1)

I 5 - 0 0
C -x - +x +x
E 5-x - x x

From recation (1) we get,

but, x << 5 Therefore,

Hence,  

ie.  

2. ...(2)

We have, and

Therefore,

  

3.

we have, ,   

and   

Therefore,


Related Solutions

Phosphoric acid, H 3 PO 4 ( aq ) , is a triprotic acid, meaning that...
Phosphoric acid, H 3 PO 4 ( aq ) , is a triprotic acid, meaning that one molecule of the acid has three acidic protons. Estimate the pH and the concentrations of all species in a 0.500 M phosphoric acid solution. [ H 3 PO 4 ] = [ H + ] = [ H 2 PO − 4 ] = [ OH − ] = [ HPO 2 − 4 ] = [ PO 3 − 4 ] =
Phosphoric acid is a triprotic acid, and the Ka values are given below. Calculate pH, pOH,...
Phosphoric acid is a triprotic acid, and the Ka values are given below. Calculate pH, pOH, [H3PO4], [H2PO4 2- ], [HPO4 - ], and [PO4 3- ] at equilibrium for a 5.00 M phosphoric acid solution. Ka1 = 7.5 x 10-3 Ka2 = 6.2 x 10-8 Ka3 = 4.2 x 10
Phosphoric acid, H3PO4(aq), is a triprotic acid. Calculate the pH and concentrations of H3O + (aq),...
Phosphoric acid, H3PO4(aq), is a triprotic acid. Calculate the pH and concentrations of H3O + (aq), H3PO4(aq), H2PO4 − (aq), HPO4 2− (aq), PO4 3− (aq), and OH− (aq) in a 0.100-M phosphoric acid solution at 25°C.
39. Phosphoric acid (H3PO4) is a triprotic weak acid. Calculate the pH, [H3PO4], [H2PO4 -], [HPO4...
39. Phosphoric acid (H3PO4) is a triprotic weak acid. Calculate the pH, [H3PO4], [H2PO4 -], [HPO4 2-], and [PO4 3-] of a 4.5 M H3PO4 aqueous solution. H3PO4 (aq) + H2O (l) ⇌ H3PO4 - (aq) + H3O+ (aq) Ka1 = 7.5 × 10-3 H3PO4 - (aq) + H2O (l) ⇌ HPO4 2- (aq) + H3O+ (aq) Ka2 = 6.2 × 10-8 HPO4 2- (aq) + H2O (l) ⇌ PO4 3- (aq) + H3O+ (aq) Ka3 = 4.2 × 10-13
Phosphoric acid is a triprotic acid (Ka1 = 6.9× 10–3, Ka2 = 6.2× 10–8, and Ka3...
Phosphoric acid is a triprotic acid (Ka1 = 6.9× 10–3, Ka2 = 6.2× 10–8, and Ka3 = 4.8× 10–13). To find the pH of a buffer composed of H2PO4–(aq) and HPO42–(aq), which pKa value would you use in the Henderson-Hasselbalch equation? Calculate the pH of a buffer solution obtained by dissolving 15.0 g of KH2PO4(s) and 33.0 g of Na2HPO4(s) in water and then diluting to 1.00 L.
Phosphoric Acid, H3PO4(aq) is a triprotic acid, meaning that one molecule of the acid has three...
Phosphoric Acid, H3PO4(aq) is a triprotic acid, meaning that one molecule of the acid has three acidic protons. Estimate the pH and the concentrations(M) of all species in a 0.300 M phosphoric acid solution. pKa1= 2.16 pKa2=7.21 pKa3=12.32 [H3PO4]= [H2PO4-]= [HPO4^2-]= [PO4^3-] [H+]= [OH-]= pH=
Phosphoric acid, H3PO4(aq), is a triprotic acid, meaning that one molecule of the acid has three...
Phosphoric acid, H3PO4(aq), is a triprotic acid, meaning that one molecule of the acid has three acidic protons. Estimate the pH, and the concentrations of all species in a 0.500 M phosphoric acid solution. pKa1= 2.16 pKa2=7.21 pKa3= 12.32 What's: H3PO4, H2PO4-, HPO4-2, PO4-3, H, OH, and pH -Thanks!
2. Phosphoric acid (H3PO4) is a triprotic acid with the following pKa values: pKa1 = 2.15...
2. Phosphoric acid (H3PO4) is a triprotic acid with the following pKa values: pKa1 = 2.15 pKa2 = 7.20 pKa3 = 12.35 a). You wish to prepare a 1.000 L of a 0.0450 M phosphate buffer at pH 6.8. Which of the following salts do you use (PICK 2) and what mass of each salt will you add to the mixture? H3PO4 (M.W.= 97.995) KH2PO4 (M.W.=136.086) Na2HPO4 (M.W.=141.959) AlPO4 (M.W.=121.953) 2 b). A concentrated phosphate buffer known as “phosphate buffered...
A 5.00 mL volume of a 0.60 M solution of phosphoric acid, H3PO4(aq), reacts with 45.00...
A 5.00 mL volume of a 0.60 M solution of phosphoric acid, H3PO4(aq), reacts with 45.00 mL of 0.25 M NaOH(aq) according to the reaction below. The temperature of the solution rises from 26.0 °C to 28.0 °C. Assume the volumes of the solutions are additive, the density of the final solution is 1.10 g mL–1 , the heat capacity of the solution is the same as water and the water produced by the reaction does not affect the volume...
Phosphoric acid is a triprotic acid with the following pKa values: pKa1=2.148 pKa2=7.198 pKa3=12.375 You wish...
Phosphoric acid is a triprotic acid with the following pKa values: pKa1=2.148 pKa2=7.198 pKa3=12.375 You wish to prepare 1.000 L of a 0.0200 M phosphate buffer at pH 7.720. To do this, you choose to mix the two salt forms involved in the second ionization, NaH2PO4 and Na2HPO4, in a 1.000 L volumetric flask and add water to the mark. What mass of each salt will you add to the mixture? mass NaH2PO4= ________g mass Na2HPO4= __________g What other combination...
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT