Question

In: Chemistry

An aqueous solution is made by dissolving 21.2 grams of ammonium phosphate in 323 grams of...

An aqueous solution is made by dissolving 21.2 grams of ammonium phosphate in 323 grams of water.


The molality of ammonium phosphate in the solution is ? m.

In the laboratory you are asked to make a 0.150 m potassium sulfide solution using 15.7 grams of potassium sulfide.  

How much water should you add?  
grams

If 20.9 grams of an aqueous solution of ammonium phosphate, (NH4)3PO4, contains 3.33 grams of ammonium phosphate, what is the percentage by mass of ammonium phosphate in the solution?

% (NH4)3PO4

How many grams of KF are there in 195 grams of an aqueous solution that is 10.8 % by weight KF.

g KF

Solutions

Expert Solution

1)

Molar mass of (NH4)3PO4,

MM = 3*MM(N) + 12*MM(H) + 1*MM(P) + 4*MM(O)

= 3*14.01 + 12*1.008 + 1*30.97 + 4*16.0

= 149.096 g/mol

mass((NH4)3PO4)= 21.2 g

use:

number of mol of (NH4)3PO4,

n = mass of (NH4)3PO4/molar mass of (NH4)3PO4

=(21.2 g)/(1.491*10^2 g/mol)

= 0.1422 mol

m(solvent)= 323 g

= 0.323 kg

use:

Molality,

m = number of mol / mass of solvent in Kg

=(0.1422 mol)/(0.323 Kg)

= 0.4402 molal

Answer: 0.440 molal

2)

Molar mass of K2S,

MM = 2*MM(K) + 1*MM(S)

= 2*39.1 + 1*32.07

= 110.27 g/mol

mass(K2S)= 15.7 g

use:

number of mol of K2S,

n = mass of K2S/molar mass of K2S

=(15.7 g)/(1.103*10^2 g/mol)

= 0.1424 mol

use:

molality = number of mol / mass of solvent in Kg

0.15 = 0.1424/ mass of solvent

mass of solvent = 0.949 Kg

= 949 g

Answer: 949 g

3)

mass % = mass of (NH4)3PO4 * 100 / mass of solution

= 3.33*100/20.9

= 15.9 %

Answer: 15.9 %

4)

mass % = mass of KF * 100 / mass of solution

10.8 = mass of KF * 100 / 195

mass of KF = 21.06 %

Answer: 21.1 %


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