Question

In: Chemistry

Express the equilibrium constant for the following reaction. 10PCl5(g) ↔ 10PCl3(g) + 10Cl2(g)

Express the equilibrium constant for the following reaction.

10PCl5(g) ↔ 10PCl3(g) + 10Cl2(g)

Solutions

Expert Solution

10PCl5(g) ↔ 10PCl3(g) + 10Cl2(g)

rate of forward reaction = Kf[PCl5]10

rate of back ward reaction = Kb[PCl3]10 [Cl2]10

at equilibrium

rate of forward reaction = rate of back ward reaction

             Kf[PCl5]10            = Kb[PCl3]10 [Cl2]10

                    Kf/Kb          = [PCl3]10 [Cl2]10/[PCl5]10

                   Kc                = [PCl3]10 [Cl2]10/[PCl5]10


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