Question

In: Chemistry

81Sr decays by positron emission with a half-life of 22.2 minutes. Starting with 885g of Sr-81,...

81Sr decays by positron emission with a half-life of 22.2 minutes. Starting with 885g of Sr-81, how much remains after 75.0 minutes?

Solutions

Expert Solution

Given :Half life : 22.2 min

Initial amount of Sr-81= [ Sr -81 ] t = 0 = 885 g  

Amount of Sr -81 left after time 75.0 min = [ Sr -81 ] t =75.0 min = ?

Time of disintegration =75.0 min

We have equation: t =2.303 /    log (N 0 / N t) -------------------> (1)

Where, is a decay constant, N 0 is the initial amount of radioactive element, N t is the amount of radioactive element after time t.

t =2.303 /    log [ Sr -81 ] t = 0 /  [ Sr -81 ] t =75.0 min

We have relation , decay constant = 0.693 / t 1/2

decay constant = 0.693 / 22.2 min = 0.03122 min -1

75.0 min =  2.303 / 0.03122 min -1 log 885 g /  [ Sr -81 ] t =75.0 min

log 885 g /  [ Sr -81 ] t =75.0 min = 75.0 min 0.03122 min -1 / 2.303

log 885 g /  [ Sr -81 ] t =75.0 min = 1.017

885 g /  [ Sr -81 ] t =75.0 min = 10 1.017

885 g /  [ Sr -81 ] t =75.0 min = 10.40

  [ Sr -81 ] t =75.0 min = 885 g / 10.40 = 85.1 g

ANSWER : Amount of Sr-81 left after 75.0 min = 85.1 g


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