In: Chemistry
81Sr decays by positron emission with a half-life of 22.2 minutes. Starting with 885g of Sr-81, how much remains after 75.0 minutes?
Given :Half life : 22.2 min
Initial amount of Sr-81= [ Sr -81 ] t = 0 = 885 g
Amount of Sr -81 left after time 75.0 min = [ Sr -81 ] t =75.0 min = ?
Time of disintegration =75.0 min
We have equation: t =2.303 / log (N 0 / N t) -------------------> (1)
Where, is a decay constant, N 0 is the initial amount of radioactive element, N t is the amount of radioactive element after time t.
t =2.303 / log [ Sr -81 ] t = 0 / [ Sr -81 ] t =75.0 min
We have relation , decay constant = 0.693 / t 1/2
decay constant = 0.693 / 22.2 min = 0.03122 min -1
75.0 min = 2.303 / 0.03122 min -1 log 885 g / [ Sr -81 ] t =75.0 min
log 885 g / [ Sr -81 ] t =75.0 min = 75.0 min 0.03122 min -1 / 2.303
log 885 g / [ Sr -81 ] t =75.0 min = 1.017
885 g / [ Sr -81 ] t =75.0 min = 10 1.017
885 g / [ Sr -81 ] t =75.0 min = 10.40
[ Sr -81 ] t =75.0 min = 885 g / 10.40 = 85.1 g
ANSWER : Amount of Sr-81 left after 75.0 min = 85.1 g