Question

In: Chemistry

what is the different between C-C-C bond angles, C-C-H bond angles and X-C-C-X torsion angles

what is the different between C-C-C bond angles, C-C-H bond angles and X-C-C-X torsion angles

Solutions

Expert Solution

Angle between two bisecting planes are called torsional angle or dihedral angle. The torsion angle, χ, which ranges from -180° to 180°

The torsion angle between X-C(1)-C(2)-X is defined by the angle between the planes formed by atoms X-C(1) and X-C(2).Angle can be 00 or 1800, it depends whether structure is cis or trans. or when the atoms are eclipsed, the dihedral angle is 00 and when the atoms are opposite, the angle is 1800.

In case of C-C-C and C-C-H bond angle, it genrates due to shape of bond instead of planes. The C atoms in alkanes are tetrahedral so their H-C-H, C-C-H, and C-C-C bond angles are all near to 109.5°.  this value occurs only when the four other atoms attached to the carbon atom are identical to each other. When they are not all identical, the bond angles differs from109.5°.


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