In: Chemistry
Rising nearly 1.68 km above Yosemite Valley and 2.68 km above sea level, Half Dome is a Yosemite icon and a great challenge to many hikers. (a) What would be the barometric pressure reading, in mmHg, at Half Dome? (b) Assume a hiker takes the same volume of air with each breath as he/she does while walking at sea level. Determine the ratio of the mass of oxygen inhaled for each breath at Half Dome compared to that at sea level.
Ans;- a) let P be the barometric pressure
P0 be the atmospreic pressure = 760mmhg
m be the mass of air = 28.9 g/mol
g be acceleration due to gravity=9.8m/s2
R=universal gas constant =8.314J/mol/K
T=temperature=273K
Let be the height at half dome
Now
=2.68-1.68
=1km
=1000m
Now,
= 760e(-28.9x9.8x1000/8.314x273)
=760x1.4
=1064mmhg
The barometric pressure at half dome is 1064mmhg
Ans b) Let ms be the mass of oxygen at sea level
mhd be the mass of oxygen at half dome
Now theoritically we know
density of air at sea level =1.225Kg/m3
Now height at half dome=1000m
density of at air at half dome = 1.202kg/m3
Now
mass = density/volume
since the volume remains same
we have
=0.98/1