Question

In: Chemistry

Given the equation 5VO2++Mn2+→5VO2++MnO4− how many H2O molecules should be added to the right side of...

Given the equation

5VO2++Mn2+→5VO2++MnO4−

how many H2O molecules should be added to the right side of the equation to balance the oxygen atoms

Solutions

Expert Solution

Given equation:

5VO2+ + Mn2+ = 5VO2+ + MnO4-

Here, two half reactions are involved:

1. Reduction half reaction (RHR)

5VO2+ = 5VO2+

5VO2+ = 5VO2+ + 5H2O (balancing oxygen atoms)

5VO2+ + 10H+ = 5VO2+ + 5H2O (balancing hydrogen atoms)

Balanced RHR: 5VO2+ + 10H+ + 5e- = 5VO2+ + 5H2O (balancing charge)

2. Oxidation half reaction (OHR)

Mn2+ = MnO4-

Mn2+ + 4H2O = MnO4- (balancing oxygen atoms)​

Mn2+ + 4H2O = MnO4- + 8H+ (balancing hydrogen atoms)​

Balanced OHR: Mn2+ + 4H2O = MnO4- + 8H+ + 5e- (balancing charge)​

By adding both the balanced RHR and OHR, we will get the complete balanced equation as follows.

5VO2+ + Mn2+ + 2H+ = 5VO2+ + MnO4- + H2O

Therefore, one H2O molecule should be added to the right side of the equation to balance the oxygen atoms


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