In: Chemistry
What is the correct formula for lithium tetrachlorocuprate(II)?
a. Li3[CuCl4]
b. Li2[CuCl4]
c. Li[CuCl4]
d. Li4[CuCl4]
e. Li2[CuCl6]
Ans. In nomenclature of complex compounds, cuprate means anionic copper complex, i.e. a Cu-complex with net negative charge on it.
Tetrachlorocuprate means a cuprate with four Cl-atoms.
So,
Tetrachlorocuprate = [CuCl4]2-
Cu is in oxidation state of +2, Cl has oxidation number of -1. So, the net charge on complex is -2 (for Cu(II)).
# To make the overall complex neutral with Li, there must be two Li-atoms (Li has oxidation number of +1).
So,
Overall complex is – Li2[CuCl4]
Therefore: lithium tetrachlorocuprate = Li2[CuCl4]
Correct option is- b. Li2[CuCl4]