Question

In: Chemistry

What is the correct formula for lithium tetrachlorocuprate(II)? a. Li3[CuCl4] b. Li2[CuCl4] c. Li[CuCl4] d. Li4[CuCl4]...

What is the correct formula for lithium tetrachlorocuprate(II)?

a. Li3[CuCl4]

b. Li2[CuCl4]

c. Li[CuCl4]

d. Li4[CuCl4]

e. Li2[CuCl6]

Solutions

Expert Solution

Ans. In nomenclature of complex compounds, cuprate means anionic copper complex, i.e. a Cu-complex with net negative charge on it.

Tetrachlorocuprate means a cuprate with four Cl-atoms.

So,

            Tetrachlorocuprate = [CuCl4]2-

Cu is in oxidation state of +2, Cl has oxidation number of -1. So, the net charge on complex is -2 (for Cu(II)).

# To make the overall complex neutral with Li, there must be two Li-atoms (Li has oxidation number of +1).

So,

            Overall complex is – Li2[CuCl4]

Therefore: lithium tetrachlorocuprate = Li2[CuCl4]

Correct option is- b. Li2[CuCl4]


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