Compare the advantages and limitations of column chromatography with those of thin-layer and gas chromatography. Discuss all 3 chromatography methods. When you would use them and in which case is each useful and not useful?
In: Chemistry
The anthocyanin in hydrangeas can be isolated and used as an environmentally friendly pH indicator for titrations. At the end of a titration reaction of a strong acid with a strong base, you have a neutral solution. What color do you expect anthocyanin to be at the end of a titration? Describe a lab experiment to support your prediction.
In: Chemistry
A 3.87 gram sample of ascorbic acid (Vitamin C) yield 5.80 grams of CO2 and 1.58 grams of H2O on combustion. What is the empirical formula of this compound? (This compound contains only C, H, and O.)
In: Chemistry
In an ideal solution of A and B, 2.75 mol are in the liquid phase and 4.255 mol are in the gaseous phase. The overall composition of the system is ZA = 0.420, and xA = 0.310. Calculate yA.
In: Chemistry
1)When one atom transfers one or more valence electrons to another atom, a(n) ___ is formed.
A.Covalent Bond
B.Ionic Bond
C.Metallic Bond
D.All of the above
2)Typically, when two atoms form a chemical bond, the expected result is that the electrons
A.Will be in the excited state
B.Will be completely removed from both atoms
C.Will compete a noble gas configuration for both atoms
D.None of the above
3)Which of the statements about ionic solids is FALSE?
A.Ionic solids conduct electricity when dissolved in water.
B.Ionic solids are good conductors of electricity.
C.Ionic solids form crystals
D.Ionic solids can be formed by reacting an alkali metal with a halogen.
4)The balanced net ionic equation for the reaction between acetic acid and sodium hydroxide is:
A.H+(aq) + OH-(aq) = H2O(l)
B.HC2H3O2(aq) + OH-(aq) = C2H3O2-(aq) + H2O(l)
C.H+(aq) + C2H3O2-(aq) + OH-(aq) = C2H3O2-(aq) + H2O(l)
D.H+(aq) + C2H3O2-(aq) + OH-(aq) = C2H3O2-(aq) + H+(aq) + OH-(a)
In: Chemistry
What is the initial pH, at half way and after 12.5 mL of NaOH 0.3235 M is used to titrate 65.00 mL of 0.1237 M HAc? Ka=1.75 x 10-5
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For calcite dissolution experiment, when you increase ionic strength from 0 (infinite diluted) to 0.1 m, how much does the solubility increase?
In: Chemistry
At 650 K, the reaction MgCO3(s)?MgO(s)+CO2(g) has Kp=0.026. A 12.5L container at 650 K has 1.0 g of MgO(s) and CO2 at P = 0.0260 atm. The container is then compressed to a volume of 0.500L . Find the Mass of MgCO3 that is formed
In: Chemistry
A titration is a procedure for determining the concentration of a solution by allowing it to react with another solution of known concentration (called a standard solution). Acid-base reactions and oxidation-reduction reactions are used in titrations. For example, to find the concentration of an HCl solution (an acid), a standard solution of NaOH (a base) is added to a measured volume of HCl from a calibrated tube called a buret. An indicator is also present and it will change color when all the acid has reacted. Using the concentration of the standard solution and the volume dispensed, we can calculate molarity of the HCl solution.
Part A
A volume of 70.0 mL of aqueous potassium hydroxide (KOH) was titrated against a standard solution of sulfuric acid (H2SO4). What was the molarity of the KOH solution if 17.7 mL of 1.50 M H2SO4 was needed? The equation is
2KOH(aq)+H2SO4(aq)→K2SO4(aq)+2H2O(l)
Express your answer with the appropriate units.
Redox titrations are used to determine the amounts of oxidizing and reducing agents in solution. For example, a solution of hydrogen peroxide, H2O2, can be titrated against a solution of potassium permanganate, KMnO4. The following equation represents the reaction:
2KMnO4(aq)+H2O2(aq)+3H2SO4(aq)→3O2(g)+2MnSO4(aq)+K2SO4(aq)+4H2O(l)
A certain amount of hydrogen peroxide was dissolved in 100. mL of water and then titrated with 1.68 M KMnO4. What mass of H2O2 was dissolved if the titration required 18.3 mL of the KMnO4 solution?
Express your answer with the appropriate units.
In: Chemistry
Calculate the pH of 1.00 L of a solution that is 0.120M in HNO2 and 0.150M in NaNO2 before and after you add 2.0mL of 15.0M HCL. [Ka(HNO2) = 4.0 x 10-4]
In: Chemistry
Prove that Inter energy is Independent of the path
In: Chemistry
a buffer solution is prepared by mixing 100cm3 aqueous NH3 0.1mol
dm-3 with 100cm3 NH4Cl mol dm-3 . Given that KB for NH3
=1.74x10^-5
...
1) calculate pH of the buffer solution.
...
2)calculate the solution after addition 50cm3 HCl of 0.1 mol
dm-3.
In: Chemistry
what volume of 0.305 M AgNO3 is required to react exactly with 155.0 ml of 0.274 Monday Na2SO4 solution?
In: Chemistry
a 0.1965g sample containing copper is analysed iodometrically. copper(ii) is reduced to copper(i) by iodide:
2Cu2+ + 4I- --> 2Cul + I2
calculate the percentage of copper in the sample if 25.0mL of 0.1005M Na2S2O3 is required for the titration of the liberated iodine.
In: Chemistry
After Carrying out the Aspirin synthesis experiment, Suggest an experiment or technique based on what you have learned in the last few weeks to confirm the preparation of Aspirin. (Give full details) Hint: You are provided with pure sample of Aspirin
In: Chemistry