Questions
At 500 °C, cyclopropane (C3H6) rearranges to propene (CH3CH=CH2): C3H6 (g) ------> CH3CH=CH2 (g) The reaction...

At 500 °C, cyclopropane (C3H6) rearranges to propene (CH3CH=CH2):

C3H6 (g) ------> CH3CH=CH2 (g)

The reaction is first order and the rate constant is 6.7 x 10-4 s-1. (a) What is the rate law for the reaction, and; (b) if the initial concentration of C3H6 is 0.100 M, what is the concentration of cyclopropane of after 20 min?

3. Butadiene (C4H6) reacts with itself at 250 °C to form a dimer with the formula C8H12.

2 C4H6 (g) ----> C8H12 (l)

The reaction is second order in C4H6. (a) What is the rate law for the reaction, and; (b) if the rate constant is 4.0 x 10-2 M-1.s-1, and the initial concentration of C4H6 is 0.200 M, how long will it take for the concentration of C4H6 to reach 0.04 M?

4.         a) In Q. 2 above what is the half life for the reaction and what is concentration of C3H6 after 3 half-lives b) In Q. 3 above how long are the first and second half-lives?

help with question 2, 3 and 4. i already did them, i just want to compared answers so please show steps.

In: Chemistry

Complete the definitions chirality litmus neutrality insoluble complexes oxidation of methyl ketones hemiacetals acetals hemiketals ketals...

Complete the definitions

chirality

litmus neutrality

insoluble complexes

oxidation of methyl ketones

hemiacetals

acetals

hemiketals

ketals

hydrolysis of ketals

In: Chemistry

Alginate and Calcium Chloride make spheres possible through spherification. Can you explain this process and talk...

Alginate and Calcium Chloride make spheres possible through spherification.
Can you explain this process and talk about how the concentration, dropping height, and rate matters?
I'll appreciate as many details as you can say :D

Also, I'm curious to know if there is an alternative to create this spheres with other reactants.


Thank you so much!

In: Chemistry

A 25.0 mL sample of 0.100 M barium chloride reacts with 40.0 mL of a 0.200...

A 25.0 mL sample of 0.100 M barium chloride reacts with 40.0 mL of a 0.200 M lead (II) sulfate solution to form barium sulfate and lead (II) chloride.

A) Write the balanced equation.

B) How many grams of lead (II) chloride will form?

C) If you make 0.560 grams of lead (II) chloride from this reaction in the lab, what is the percent yield?

D) How many grams of excess reagent are left over?

In: Chemistry

1) Constant-volume calorimeters are sometimes calibrated by running a combustion reaction of known ΔE and measuring...

1) Constant-volume calorimeters are sometimes calibrated by running a combustion reaction of known ΔE and measuring the change in temperature. For example, the combustion energy of glucose is 15.57 kJ/g. When a 2.500 g sample of glucose burns in a constant volume calorimeter, the calorimeter temperature increases from 21.45 to 23.34°C. Find the total heat capacity of the calorimeter (in kJ/K).

2)An electrical heater is used to add 18.25 kJ of heat to a constant-volume calorimeter. The temperature of the calorimeter increases by 3.40°C. When 2.25 g of ethanol (C2H5OH) is burned in the same calorimeter, the temperature increases by 12.45°C. Calculate the molar heat of combustion for ethanol (enter in kJ).

3)A 0.90 g sample of caffeine, C8H10N4O2, burns in a constant-volume calorimeter that has a heat capacity of 7.85 kJ/K. The temperature increases from 298.25 K to 303.34 K. What is the molar heat of combustion of caffeine (in kJ).

4)Use standard enthalpies of formation to determine ΔHorxnfor:

2Al(s) + 3Cl2(g) → 2AlCl3(s)   Find the change in internal energy for this reaction. Enter in kJ.

5)Use standard enthalpies of formation to determine ΔHorxn for:

2NH3(g) + 3O2(g) + 2CH4(g) → 2HCN(g) + 6H2O(g) Find the change in internal energy for this reaction. Enter in kJ.

In: Chemistry

Second eyes for a final draft please- A small baggie of glucose solution is placed in...

Second eyes for a final draft please-

A small baggie of glucose solution is placed in a small beaker of distilled water. We pulled a sample of water (colorless) from the bottom of the beaker and add Benedict solution (light blue) to it which turned it to a light blue color. Adding Benedict solution to glucose tests for presence of reducing sugars that have the aldehyde functional group – CHO (or, free ketone group I.e. alpha-hydroxy ketone, too). When the Benedict solution was added, the glucose solution immediately takes the color of Benedict's reagent and turns it to light blue. When the mixture was heated in boiling distilled water, aldehyde group gets oxidized by accepting an O-atom from OH- and gives up and electron that copper ion (Cu2+) accepts and then become reduced which turns Benedict's solution and sugar into an orange color indicating a positive result due to the color change proving diffusion occurred. Test was not redone. Our group and the group we compared our results with had same results and color.  

In: Chemistry

a.) How many grams of NH3 can be produced from 4.19 mol of N2 and excess...

a.) How many grams of NH3 can be produced from 4.19 mol of N2 and excess H2? Express your answer numerically in grams.

b.) How many grams of H2 are needed to produce 11.70g of NH3

c.) How many molecules (not moles) of NH3 are produced from 2.64x10^-4 g of H2

In: Chemistry

Suppose that you have 125 mL of a buffer that is 0.260 M in both hydrofluoric...

Suppose that you have 125 mL of a buffer that is 0.260 M in both hydrofluoric acid (HF) and its conjugate base (F-). Calculate the maximum volume of 0.400 M HCl that can be added to the buffer before its buffering capacity is lost. Please help!!

In: Chemistry

The equilibrium constant, K, for the following reaction is 10.5 at 350 K. 2CH2Cl2(g) =CH4(g) +...

The equilibrium constant, K, for the following reaction is 10.5 at 350 K.

2CH2Cl2(g) =CH4(g) + CCl4(g)


An equilibrium mixture of the three gases in a 1.00 L flask at 350 K contains 5.12×10-2 M CH2Cl2, 0.166 M CH4 and 0.166 M CCl4. What will be the concentrations of the three gases once equilibrium has been reestablished, if 0.121 mol of CH4(g) is added to the flask?

[CH2Cl2] = _________M
[CH4] = _________ M
[CCl4] = _________ M

In: Chemistry

A beaker with 175 ml of an acetic acid buffer with a pH of 5.0 is...

A beaker with 175 ml of an acetic acid buffer with a pH of 5.0 is sitting on a benchtop. The total molsrity of acid and conjugate base in this buffer is 0.10 mol/L. A student adds 6.30 mL of a 0.340 mol/L HCl solution to the beaker. How much will the pH change? The pKa of acetic acid is 4.760.

In: Chemistry

Chemistry of lipid oxidation? –State specific aspects (aromas, colors) that play into this

Chemistry of lipid oxidation?

–State specific aspects (aromas, colors) that play into this

In: Chemistry

An aqueous solution contains 0.480 M acetic acid. How many mL of 0.327 M potassium hydroxide...

An aqueous solution contains 0.480 M acetic acid. How many mL of 0.327 M potassium hydroxide would have to be added to 250 mL of this solution in order to prepare a buffer with a pH of 4.680?

(please explain. thank you!)

In: Chemistry

Balance each of the following half-reactions, assuming that they occur in basic solution. CH3OH(aq)?CH2O(aq)

Balance each of the following half-reactions, assuming that they occur in basic solution. CH3OH(aq)?CH2O(aq)

In: Chemistry

A certain first-order reaction has a rate constant of 3.00×10−2 s−1s−1 at 21 ∘C∘C. What is...

A certain first-order reaction has a rate constant of 3.00×10−2 s−1s−1 at 21 ∘C∘C. What is the value of kk at 51 ∘C∘C if EaEaE_1 = 76.0 kJ/molkJ/mol ?

Express your answer using two significant figures.

Another first-order reaction also has a rate constant of 3.00×10−2 s−1s−1 at 21 ∘C∘C. What is the value of kk at 51 ∘C∘C if EaEaE_2 = 110 kJ/molkJ/mol ?

Express your answer using two significant figures.

In: Chemistry

Which of the following are generally required in a E2 reaction? Choose all that apply. A....

Which of the following are generally required in a E2 reaction? Choose all that apply.

A. strong base

B. anti-coplanar orientation of eliminated groups

C. Primary or secondary substrate

D. Good leaving group

E. strong nucleophile

In: Chemistry