For the reaction 2 A(aq) <---> B(aq) + C(aq), the standard Gibbs free enthalpy change is 1.69 kJ at 25oC. The initial concentration of A(aq) is 0.549 M, the initial concentration of B(aq) is 0.327 M, and the initial concentration of C(aq) is 0.234 M. What would be the concentration of A(aq) (in mol/L) once we attain equilibrium (we are still at 25oC)?
In: Chemistry
If 20.00 mol of helium gas is at 17.0 ∘C and a gauge pressure of 0.320 atm .
Calculate the temperature in celcius if the gas is compressed to precisely half the volume at a gauge pressure of 1.00 atm. Original volume is 0.3608m3
In: Chemistry
Calculate the height of a column of carbon tetrachloride, CCl4(l), with a density of 1.59 g/mL that exerts the same pressure as a 15.2 cm column of Mercury, Hg(l), that has a density of 13.6 g/ml. Express your answer in meters. Please only enter the numerical value of your answer.
In: Chemistry
A sample of a concentrated fluorescent reagent was serially diluted with three steps using a variable volume 100 to 500 μL micropipetor and 10.00 mL Class A volumetric flasks. The concentrated reagent had a fluorescent signal of 653.4 and the diluted sample produced 0.057 fluorescence units. Unfortunately the steps followed for the dilution were lost. What were those steps?
In: Chemistry
In your own words, clearly explain the process of electrolysis of water. Include a description of the equipment involved, as well as the resulting chemical reaction(s).
In: Chemistry
Part A What is the pH of a buffer prepared by adding 0.809 mol of the weak acid HA to 0.608 mol of NaA in 2.00 L of solution? The dissociation constant Ka of HA is 5.66×10−7. Part B What is the pH after 0.150 mol of HCl is added to the buffer from Part A? Assume no volume change on the addition of the acid. (Express answer to 3 decimal places) Part C What is the pH after 0.195 mol of NaOH is added to the buffer from Part A? Assume no volume change on the addition of the base.
In: Chemistry
A voltaic cell is constructed that uses the following reaction
and operates at 298 K:
Zn(s)+Ni2+(aq)→Zn2+(aq)+Ni(s).
a. What is the emf of this cell when [Ni2+]= 2.10 M and [Zn2+]= 0.160 M ?
b. What is the emf of the cell when [Ni2+]= 0.100 M and [Zn2+]= 0.860 M ?
Thanks!
In: Chemistry
The atmosphere slowly oxidizes hydrocarbons in a number of steps
that eventually convert the hydrocarbon into carbon dioxide and
water. The overall reactions of a number of such steps for methane
gas is as follows:
CH4(g)+5O2(g)+5NO(g)→CO2(g)+H2O(g)+5NO2(g)+2OH(g)
Suppose that an atmospheric chemist combines 145 mL of methane at
STP, 895 mL of oxygen at STP, and 54.5 mL of NO at STP in a 2.0
−Lflask. The reaction is allowed to stand for several weeks at 275
K.
Part A
If the reaction reaches 90.0% of completion (90.0% of the limiting reactant is consumed), what are the partial pressures of each of the reactants in the flask at 275 K?
Enter your answers numerically separated by commas.
|
|
||||
| PCH4,PO2,PNO= | atm |
Part B
If the reaction reaches 90.0% of completion (90.0% of the limiting reactant is consumed), what are the partial pressures of each of the products in the flask at 275 K?
Enter your answers numerically separated by commas.
|
|
||||
| PCO2,PH2O,PNO2,POH= | atm |
Part C
What is the total pressure in the flask?
In: Chemistry
Calculate the freezing point and boiling point in each solution, assuming complete dissociation of the solute.
a)Calculate the freezing point of a solution containing 10.8
g FeCl3 in 172 g water.
b)Calculate the boiling point of a solution above.
c)Calculate the freezing point of a solution containing 4.3 % KCl
by mass (in water).
d)Calculate the boiling point of a solution above.
e)Calculate the freezing point of a solution containing 0.155 m MgF2.
f)Calculate the boiling point of a solution above.
In: Chemistry
Which of the following are true statements about equilibrium systems?
True/False For the following reaction at equilibrium:
2 H2(g) + O2(g) ⇌ 2 H2O(g)
the equilibrium will shift to the left if the volume is
doubled.
True/False For the following reaction at equilibrium:
H2(g) + F2(g) ⇌ 2HF(g)
removing H2 will decrease the amount of F2
present once equilibrium is reestablished.
True/False For the following reaction at equilibrium:
CaCO3(s) ⇌ CaO(s) + CO2(g)
adding more CaCO3 will shift the equilibrium to the
right.
True/False Increasing the temperature of an exothermic reaction
shifts the equilibrium position to the right.
True/False For the following reaction at equilibrium:
CaCO3(s)⇌ CaO(s) + CO2(g)
increasing the total pressure by adding Ar(g) will shift the
equilibrium to the right.
In: Chemistry
A piece of copper wire is 50ft long and has a dimater of 2.0 mm. Copper has a denisty of 8.92 g/cm3. What is the mass of copper? Express the answer in kg. (1ft = 30.48 cm, 1 cm = 10 mm and Volume is 3.14 x r2x1)
Please explain and help ! :(
In: Chemistry
One electrode compartment consists of an aluminum strip placed in a solution of Al(NO3)3, and the other has a nickel strip placed in a solution of NiSO4. The overall cell reaction is
2Al(s)+3Ni2+(aq)?2Al3+(aq)+3Ni(s)
1. What is being reduced?
2. Write the half-reactions that occur in the two electrode compartments.
anode reaction:
cathode reaction:
In: Chemistry
How many grams of Na2CO3 should be mixed with 5.00 g of NaHCO3 to produce 100 mL of buffer with a pH of 10.00? What volume of 0.01 M NaOH must be added to this solution to achieve a pH of 11.25? (pKa1 is 6.35; pKa2 is 10.53)
In: Chemistry
Using energy level diagrams, predict the relative stability of a Br2 molecule as well as the first excited state.
In: Chemistry