76
What is the total sample size (in grams) for a sample of ethanol (CH3CH2OH) which contains 2.51 g of oxygen?
77.
What is the total sample size (in grams) for a sample of sodium nitrite which contains 3.54 g of oxygen?
In: Chemistry
What is the pH at the equivalence point in the titration of a 22.6 mL sample of a 0.371 M aqueous acetic acid solution with a 0.353 M aqueous barium hydroxide solution?
pH =
In: Chemistry
If a solution of NaOH has a 20% mass percent of NaOH and a density of 1.22 g/ml, what is the molarity of this solution ?
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Draw a schematic diagram for a Perkin Elmer ultraviolet-visible spectrophotometer, clearly and specifically identifying each important part.
b. Draw a schematic diagram for a Shimadzu spectro-fluorometer, clearly and specifically identifying each important part.
c. Compare a PM tube, a PDA, and a thermocouple with respect to two different aspects.
In: Chemistry
Use your calculated value of Ksp (1.35 x 10^-7) and Kf (1140) to explain why CdC2O4 is dissolved by ammonia.
How would the formation constant for [Cd(NH3)4 +2] be affected (increase, decrease, or no change) if not all of the CdC2O4 precipitate reacted with NH3?
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Thanks in advance!!!
In: Chemistry
The decomposition of XY is second order in XY and has a rate constant of 6.94×10−3 M−1⋅s−1 at a certain temperature.
If the initial concentration of XY is 0.160 M , how long will it take for the concentration to decrease to 6.00×10−2 M ? Express your answer using two significant figures.
If the initial concentration of XYXY is 0.050 MM, what is the concentration of XYXY after 500 ss ?
Express your answer using two significant figures.
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Reaction enthalpy for ethanol oxidation, C2H5OH+3O2 -> 2CO2 + 3H2O is 1257 kJ/mole.
Energy content per mol fuel ______kJ Energy content per gram fuel = ____________ kJ
Energy released per mol CO2 formed ________ kJ Energy released per mol O2 consumed= ______ kJ
Moles of CO2 formed per 1000 kJ energy released ___________
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a) Explain oxidative addition and carbonyl insertion reactions in organometallic chemistry with
appropriate examples.
b) Explain pictorially the σ- and π-bonding in metal-carbonyl compounds and comment on the synergistic effect.
c) What are the experimental evidences and how they support synergistic effect in metal carbonyl bonding?
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Explain the sublimation and vaporization processes. How does the condensation process relate to vaporization and how does deposition relate to sublimation? Give an example of each process
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1. Use this data table for the bromination of acetone to answer the following questions;
|
Experiment |
[CH3COCH3] (M) |
[Br2] (M) |
[H+] (M) |
Rate (M s-1) |
|
1 |
0.3 |
0.05 |
0.05 |
0.000057 |
|
2 |
0.3 |
0.10 |
0.05 |
0.000057 |
|
3 |
0.3 |
0.05 |
0.10 |
0.000120 |
|
4 |
0.4 |
0.05 |
0.20 |
0.000310 |
|
5 |
0.4 |
0.05 |
0.05 |
0.000076 |
a) Determine the reaction order with respect to each of the three reactants and write the rate law.
b) What is the value of the rate constant including proper units?
In: Chemistry
For each of the transition metal complex ions
(a) [Ti(NH3)6]2+
(b) [Cr(H2O)4(OH)2]1-
(c) trans–[Pt(CN)2(en)2]2+
(i) Draw the structure of the transition metal complex ion. Show
the charge on the
complex.
(ii) Determine the number of d electrons.
(iii) Draw the ground state arrangement of the d electrons in the
ground state.
(iv) Calculate the LFSE (in units of Δo or ΔT) for each
complex.
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1) A) Draw the dipeptide Y-C at pH 7 and clearly label the peptide bond to be broken in the presence of chymotrypsin.
B) Draw the five-step mechanism for the chymotrypsin clevage of the dipeptide.
C) Label the transition state each time it is formed.
D) What mechanism is used to describe this bisubstrate reaction?
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1. For the reaction: 2Mg(s) + O2(g) → 2MgO Calculate the percent yield if 10g of Mg and 15g of O2 react, and 15.0g MgO was actually obtained.
2. For the reaction: H2(g) + Cl2(g) → HCl(g) (is this balanced?) calculate the mass, in grams of Hydrogen Chloride produced when H2 reacts with 25.0g Cl2.
In: Chemistry
calculate the mass percent of oxalate ion in H2C2O4*2H2O and (NH4)2C2O4*H2O
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