Questions
mL HCl added pH 0.00 11.86 25.0 10.71 50.0 6.09 A titration of 25.0 mL of...

mL HCl added

pH

0.00

11.86

25.0

10.71

50.0

6.09

A titration of 25.0 mL of 0.100 M triethylamine ((CH3CH2)3N) was performed with 0.0500 M HCl. Given the following data calculate the pKa for triethylammonium ion.

In: Chemistry

Calculate the pH change that results when 15 mL of 2.6 M HCl is added to...

Calculate the pH change that results when 15 mL of 2.6 M HCl is added to 600. mL of each of the following solutions. (See the appendix.)

(a) pure water
  

(b) 0.10 M CH3COO?


(c) 0.10 M CH3COOH


(d) a solution that is 0.10 M in each CH3COO? and CH3COOH.

Table 3 An Acid-base table

Acid Name ConjugateAcid Ka pKa Conjugate Base Base Name
perchloric acid HClO4 >>1 < 0 ClO41- perchlorate ion
hydrohalic acid HX (X=I,Br,Cl) >>1 < 0 X1- halide ion
sulfuric acid H2SO4 >>1 < 0 HSO41- hydrogen sulfate ion
nitric acid HNO3 >>1 < 0 NO31- nitrate ion
hydronium ion H3O1+ 1.0 0.00 H2O water
iodic acid HIO3 0.17 0.77 IO31- iodate ion
oxalic acid H2C2O4 5.9 x 10-2 1.23 HC2O41- hydrogen oxalate ion
sulfurous acid H2SO3 1.5 x 10-2 1.82 HSO31- hydrogen sulfite ion
hydrogen sulfate ion HSO41- 1.2 x 10-2 1.92 SO42- sulfate ion
phosphoric acid H3PO4 7.5 x 10-3 2.12 H2PO41- dihydrogen phosphate ion
hydrofluoric acid HF 7.2 x 10-4 3.14 F1- fluoride ion
nitrous acid HNO2 4.0 x 10-4 3.40 NO21- nitrite ion
lactic acid HC3H5O3 6.4 x 10-5 3.85 C3H5O31- lactate ion
formic acid HCHO2 1.8 x 10-4 3.74 CHO21- formate ion
hydrogen oxalate ion HC2O41- 6.4 x 10-5 4.19 C2O42- oxalate ion
hydrazoic acid HN3 1.9 x 10-5 4.72 N31- azide ion
acetic acid HC2H3O2 1.8 x 10-5 4.74 C2H3O21- acetate ion
carbonic acid H2CO3 4.3 x 10-7 6.37 HCO31- hydrogen carbonate ion
hydrogen sulfite ion HSO31- 1.0 x 10-7 7.00 SO32- sulfite ion
hydrosulfuric acid H2S 1.0 x 10-7 7.00 HS1- hydrogen sulfide ion
dihydrogen phosphate ion H2PO41- 6.2 x 10-8 7.21 HPO42- hydrogen phosphate ion
hypochlorous acid HClO 3.5 x 10-8 7.46 ClO1- hypochlorite ion
ammonium ion NH41+ 5.6 x 10-10 9.25 NH3 ammonia
hydrocyanic acid HCN 4.0 x 10-10 9.40 CN1- cyanide ion
hydrogen carbonate ion HCO31- 4.7 x 10-11 10.33 CO32- carbonate ion
hydrogen phosphate ion HPO42- 4.8 x 10-13 12.32 PO43- phosphate ion
hydrogen sulfide ion HS1- 1.3 x 10-13 12.89 S2- sulfide ion
water H2O 1.0 x 10-14 14.00 OH1- hydroxide ion
ammonia NH3 <<10-14 NH21- amide ion
hydroxide ion OH1- <<10-14 O2- oxide ion

In: Chemistry

The Clausius-Clapeyron equation and the Antoine equation. The vapor pressure of a liquid can be written...

The Clausius-Clapeyron equation and the Antoine equation. The vapor pressure of a liquid can be written in the empirical form known as the Antoine equation, ln (p / p ◦ ) = A1 − (A2 /(T + A3)) where A1, A2, and A3 are empirical constants determined from measurements, and T is the temperature in Kelvin.

(a) Starting with this equation, derive an equation for the enthalpy of vaporization as a function of temperature.

(b) For ethanol (l), A1 = 23.58, A2 = 3.67 × 103 , A3 = −46.702, and p ◦ = 1 Pa. Given that the standard pressure is 1 bar = 1.01325 × 105 Pa, what is the standard boiling temperature?

(c) Calculate ∆h at 298 K and at the standard boiling temperature.

In: Chemistry

The boiling point elevation constant for water is 0.51 degrees C/m. What is the boiling point...

The boiling point elevation constant for water is 0.51 degrees C/m. What is the boiling point of a solution made by dissolving 21.6g of a non-ionizing solute with a molar mass of 103.5 g/mol in 187g of water?

In: Chemistry

Motion of an election in a hydrogen atom corresponds to the potential energy U(r) = −...

Motion of an election in a hydrogen atom corresponds to the potential energy U(r) = − e^2/(4πε0r) ,

4πε0 r which comes from the Coulomb attraction between the electron and the proton. Using the uncertainty

relation between the momentum of the electron, and its position, estimate the size of the hydrogen atom.

In: Chemistry

Consider the reaction: SO2Cl2(g)⇌SO2(g)+Cl2(g) Kp=2.91×103 at 298 K In a reaction at equilibrium, the partial pressure...

Consider the reaction:
SO2Cl2(g)⇌SO2(g)+Cl2(g) Kp=2.91×103 at 298 K
In a reaction at equilibrium, the partial pressure of SO2 is 0.135 atm and that of Cl2 is 0.342 atm .

Part A

What is the partial pressure of SO2Cl2 in this mixture?

In: Chemistry

The Li2+ ion is hydrogenic and has a Lyman series at 740747 cm-1, 877924 cm-1, 925933...

The Li2+ ion is hydrogenic and has a Lyman series at 740747 cm-1, 877924 cm-1, 925933 cm-1 and beyond. Show that the energy levels are of the form –hcR/n2 and find the value of R for this ion. Go on to predict the wavenumbers of the two longest wavelength transitions of the Balmer series of the ion and find the ionization energy of the ion.

In: Chemistry

Given the two reactions H2S⇌HS−+H+,   K1 = 9.24×10−8, and HS−⇌S2−+H+,   K2 = 1.15×10−19, what is the equilibrium constant...

Given the two reactions

H2S⇌HS−+H+,   K1 = 9.24×10−8, and

HS−⇌S2−+H+,   K2 = 1.15×10−19,

what is the equilibrium constant Kfinal for the following reaction?

S2−+2H+⇌H2S

Part B

Given the two reactions

PbCl2⇌Pb2++2Cl−,   K3 = 1.74×10−10, and

AgCl⇌Ag++Cl−,   K4 = 1.26×10−4,

what is the equilibrium constant Kfinal for the following reaction?

PbCl2+2Ag+⇌2AgCl+Pb2+

In: Chemistry

What is the vapor pressure of a solution prepared by adding 50.0 g of NaCl to...

What is the vapor pressure of a solution prepared by adding 50.0 g of NaCl to 250. g of pure water at 25 oC? (Water has a vapor pressure of 0.036atm at 25 oC)

0.006 atm
0.004 atm
0.030 atm
0.032 atm
0.034 atm
0.002 atm

In: Chemistry

Explain why either greatly decreasing or increasing the percentage of oxygen in the atmosphere is dangerous.

Explain why either greatly decreasing or increasing the percentage of oxygen in the atmosphere is dangerous.

In: Chemistry

1)What are amino acids? Amino group, carboxyl end, what is the side chain of an amino...

1)What are amino acids? Amino group, carboxyl end, what is the side chain of an amino acid?

2)What are essential and non-essential amino acid.

3)Which are the essential amino acids?

4)Classify the amino acids based on polarity of the R group:

In: Chemistry

1. The preparation of nanoparticle solutions adds a reducing reagent, sodium borohydride, to an oxidizing agent,...

1. The preparation of nanoparticle solutions adds a reducing reagent, sodium borohydride, to an oxidizing agent, hydrogen peroxide. Is it concievable that these two reagents would react with each other?

2. Why is it important to force the regression line in the Beer's Law plot of absorbance vs. concentration to go through the origin? Would adding the point (0,0) to your data set have the same effect? Why or why not?

I'm in intro chem so pleasee give in simple terms. Don't go too into depth

In: Chemistry

Consider an open system that is in equilibrium with 10^-2 atm CO2 (g). You have no...

Consider an open system that is in equilibrium with 10^-2 atm CO2 (g). You have no other information about the system. Henry's Law telss us that KhCI2=H2CO3/pCO2= 10^-1.5 M-atm^-1

pKa1 is 6.3 (for H2CO3* dissassociation) and pKa2 is 10.3 (for HCO3- dissassociation). What is the [HCO3*], and [CO3^2-] if the pH of the solution is 5, 7,9?


In: Chemistry

Methane gas (CH4) is burned in a combustor with a given percentage of excess air. The...

Methane gas (CH4) is burned in a combustor with a given percentage of excess air. The pressure and temperature of both the air and fuel are 101 kPa and 298 K respectively. Assume that the mole fractions are 79% nitrogen and 21 % oxygen for air (use M=28.97 kg/kmol and R=0.287 kJ/kg-K) and that water is a vapor in the exhaust. Given the values below, determine the following:

--Given Values--

m_fuel (kg) = 100

Excess Air = 25%

a) Determine the air fuel ratio (kmol_air/kmol_fuel) Answer=11.905 +/- 7.9E-02

b) Determine the amount (kmol) of fuel burned. Answer=6.2344 +/- 4.2E-02

c) Determine the amount (kmol) of air used. Answer=74.219 +/- 4.9E-01

d) Determine the amount (kmol) of CO2 produce Answer=6.2344 +/- 4.2E-02

e) Determine the amount (kmol) of H2O produced. Answer=12.4688 +/- 8.3E-02

f) Determine the amount (kmol) of N2 produced. Answer=58.6332 +/- 3.9E-01

g) Determine the amount (kmol) of O2 produced Answer=3.1172 +/- 2.1E-02

h) Determine the Enthalpy (kJ) of the reactants. Answer=-466646 +/- 3.1E+03

i) Determine the adiabatic flame temperature (K). Answer=2015.16 +/- 1.3E+01

j) Determine the Enthalpy (kJ) of CO2 in the products Answer=-1877561 +/- 1.3E+04

k) Determine the Enthalpy (kJ) of H2O in the products. Answer=-2099174 +/- 1.4E+04

l) Determine the Enthalpy (kJ) of N2 in the products. Answer=3323766 +/- 2.2E+04

m) Determine the Enthalpy (kJ) of O2 in the products. Answer=186323 +/- 1.2E+03

In: Chemistry

A 2.700×10−2 M solution of NaCl in water is at 20.0∘C. The sample was created by...

A 2.700×10−2 M solution of NaCl in water is at 20.0∘C. The sample was created by dissolving a sample of NaCl in water and then bringing the volume up to 1.000 L. It was determined that the volume of water needed to do this was 999.3 mL . The density of water at 20.0∘C is 0.9982 g/mL.

Part A

Calculate the molality of the salt solution.

Express your answer to four significant figures and include the appropriate units.

Part B

Calculate the mole fraction of salt in this solution.

In: Chemistry