You would like to make 100.00 mL of a 4.76 pH acetic acid/acetate buffer, in which the acid concentration is 0.070M. Write the reaction of the buffer with HCl solution. How many mL of 0.100 M HCl can react with the buffer before it is exhausted? And Write the reaction of the buffer with NaOH solution. How many mL of 0.100 M NaOH can react with the buffer before it is exhausted?
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#16.110 A 130.0 −mL sample of a solution that is 2.9×10−3 M in AgNO3 is mixed with a 225.0 −mL sample of a solution that is 0.10 M in NaCN.
After the solution reaches equilibrium, what concentration of Ag+(aq) remains?
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Predict the colors that the following aqueous solutions will produce in a flame test:
1. CaF2(aq)
2. NaOH(aq)
3. CuCO3(aq)
An explanation for why each aqueous solution is their respective color would aid me in understanding the concept. Thank you so much!
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85. Antimony pentachloride decomposes according to this
equation:
SbCl5(g) ⇌ SbCl3(g) + Cl2(g)
An equilibrium mixture in a 5.00-L flask at 448 °C contains 3.85 g
of SbCl5, 9.14 g of SbCl3, and 2.84 g of Cl2. How many grams of
each will be found if the mixture is transferred into a 2.00-L
flask at the same temperature?
89. A 1.00-L vessel at 400 °C contains the following equilibrium
concentrations: N2, 1.00 M; H2, 0.50 M; and NH3, 0.25 M. How many
moles of hydrogen must be removed from the vessel to increase the
concentration of nitrogen to 1.1 M? The equilibrium reaction
is
N2(g) + 3H2(g) ⇌ 2NH3(g)
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Describe the three sources of loss in the lab preparation of methyl benzoate from benzoic acid.
One source is mechanical.
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A sample of cells with a total receptor concentration of 50 mM was incubated with a ligand concentration of 100 mM. Following the incubation period, the concentration of unbound receptors was determined to be 15 mM. What is the Kd for the receptor-ligand interaction?
A) 28 mM
B) 43 mM
C) 143 mM
D) 217 mM
E) 333 mM
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1.The Cu2+ ions in this experiment are produced by the reaction of 1.0g of copper turnings with excess nitric acid. How many moles of Cu2+ are produced?
2. Why isn't hydrochloric acid used in a direct reaction with copper to prepare the CuCl2 solution?
3. How many grams of metallic copper are required to react with the number of moles of Cu2+ calculated in Problem 1 to form the CuCl? The overall reaction can be taken to be: Cu2+(aq) + 2Cl-(aq) + Cu(s) -----> 2CuCl(s)
4. What is the maximum mass of CuCl that can be prepared from the reaction sequence of this experiment, using 1.0g of Cu turnings to prepare the Cu2+ solution?
5. A sample of the compound prepared in this experiment , weighing 0.1021g, is dissolved in HNO3, and diluted to a volume of 100 ml. A 10ml aliquot of that solution is mixed with 10 mL 6M NH3. The [Cu(Nh3)4]2+ in the resulting solution is found to be 5.16 x 10^-3 M.
a. How many moles of Cu were in the original sample, which had been effectively diluted to a volume of 200 mL.
b. How many grams of Cu were in the sample?
c. How many grams of Cl were in the sample? How many moles?
d. What is the formula of the copper chloride compound?
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describe how you would prepare 1.25L of a 0.025 M sucrose solution from a stock solution with concentration of 5.00 M.
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1.Pyridine is a weak base that is used in the manufacture of pesticides and plastic resins. It is also a component of cigarette smoke. Pyridine ionizes in water as follows: C5H5N+H2O⇌C5H5NH++OH− C 5 H 5 N + H 2 O ⇌ C 5 H 5 N H + + O H − The pKb p K b of pyridine is 8.75. What is the pH p H of a 0.320 M M solution of pyridine? Express the pH p H numerically to two decimal places.
2.
Benzoic acid is a weak acid that has antimicrobial properties. Its sodium salt, sodium benzoate, is a preservative found in foods, medications, and personal hygiene products. Benzoic acid dissociates in water:
C6H5COOH⇌C6H5COO−+H+C6H5COOH⇌C6H5COO−+H+
The pKapKa of this reaction is 4.2. In a 0.51 MM solution of benzoic acid, what percentage of the molecules are ionized?
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Is the reduction of benzoin to hydrobenzoin using NaBH4 and EtOH stereoselective: will only meso (cis) product be formed or a mixture of meso/racemic products?
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TYPED ONLY: Choose an organic compound to describe in depth; do not choose a nonmetal already selected by another student. Include information on whether it is found in nature, how it can be synthesized, its physical and chemical properties, and its uses or applications.
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Which reactions in the citric acid cycle are irreversible under physiological conditions, and for each of these reactions, explain why the reaction is irreversible.
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