In: Chemistry
The ?a of a monoprotic weak acid is 0.00732. What is the percent ionization of a 0.123 M solution of this acid?
Percent ionization: %
Answer:- % ionisation = 21.60%
Given:-
Ka = 0.00732
[HA](initial) = 0.123 M
Let the ionisation of acid HA is
Consider 'x' moles of acid ionizes
Now we construct ICE table
Initial | 0.123 - 0 0 |
Change | -x - +x +x |
Equilibrium | 0.123-x - x x |
Now, Ka is given by
...(1)
from ICE table we get,
ie ....(2)
eq(2) is quadratic equation its roots are given by
and
and
ie
and
ie
and
and
and
but 'x' is a concentration and it can't have negative value
Hence,
Therefore,
Now, % ionisation is