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The ?a of a monoprotic weak acid is 0.00732. What is the percent ionization of a...

The ?a of a monoprotic weak acid is 0.00732. What is the percent ionization of a 0.123 M solution of this acid?

Percent ionization: %

Solutions

Expert Solution

Answer:- % ionisation = 21.60%

Given:-

Ka = 0.00732  

[HA](initial) = 0.123 M

Let the ionisation of acid HA is

  

Consider 'x' moles of acid ionizes

Now we construct ICE table

     
Initial 0.123 - 0 0
Change -x - +x +x
Equilibrium 0.123-x - x x

Now, Ka is given by

...(1)

from ICE table we get,

ie   ....(2)

eq(2) is quadratic equation its roots are given by

and   

  

and

ie

and

ie

and

and

and

but 'x' is a concentration and it can't have negative value

Hence,

Therefore,

Now, % ionisation is


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