Question

In: Chemistry

Consider the reacton of bromine and chlorine gas to form BrCl where Kp=1.11X10^-4 at 150K. A...

Consider the reacton of bromine and chlorine gas to form BrCl where Kp=1.11X10^-4 at 150K. A reaction mixture initially contains a bromine partial pressure of 755 torr and a chlorine partial pressure of 735torr at 150K. Calculate the equilibrium partial pressure of BrCl at 25oC

Solutions

Expert Solution

                   Br2 + Cl2 -----------> 2BrCl

      I          755     735                  0

      C         -x      -x                    2x

      E      755-x   735-x              2x

               kp   = P2BrCl/PBr2 PCl2

             1.11*10-4 = (2x)2/(755-x)(735-x)

            1.11*10-4 *(755-x)(735-x)   = 4x2

                  x   = 3.9

             [BrCl] = 2x = 2*3.9 = 7.8torr


Related Solutions

Bromine chloride, BrCl, decomposes to form chlorine and bromine. At a certain temperature the equilibrium constant...
Bromine chloride, BrCl, decomposes to form chlorine and bromine. At a certain temperature the equilibrium constant for the reaction is 11.1 and the equilibrium mixture contains 4.00 mol Cl 2. How many moles of Br2 and BrCl are present in the equilibrium mixture?
If 22.8 grams of bromine and 10.1 grams of chlorine combine to form bromine monochloride, how...
If 22.8 grams of bromine and 10.1 grams of chlorine combine to form bromine monochloride, how many grams of bromine monochloride must form?
Bromine chloride, BrCl, a reddish covalent gas with properties similar to Cl2 , may eventually replace...
Bromine chloride, BrCl, a reddish covalent gas with properties similar to Cl2 , may eventually replace Cl2 as a water disinfectant. One mole of Chlorine gas and one mole of Bromine gas are enclosed in a 5.00 Liter flask and allowed to reach equilibrium at a certain temperature. Show all work                       Cl2 (g) + Br2 (g) <-----> 2BrCl (g)      Kc= 4.7 x 10-2 A) What percent of the Chlorine has reacted at equilibrium? B) What weight (in grams) of...
Carbon Minoxide and Chlorine gas react to form phosgene: CO(g) + Cl2(g) <==> COCl2(g) Kp=3.10 at...
Carbon Minoxide and Chlorine gas react to form phosgene: CO(g) + Cl2(g) <==> COCl2(g) Kp=3.10 at 700 K If a reaction mixture initially contains 404 torr of CO and 257 torr of Cl2, what is the mole fraction of COCl2 when equilibrium is reached? Mole Fraction COCl2= ?
1) Extrapolating from your knowlege of the structure of the other halogens (Chlorine = gas, bromine...
1) Extrapolating from your knowlege of the structure of the other halogens (Chlorine = gas, bromine = liquid ,and Iodine = solid), what is likely to be the molecular formula for astatine? Explain. 2) What are the likely physical states of (Gas, liquid, or solid) at room temperature? Explain your answer using your knowledge of the physical states of the other halogens. a) astatine b) bromine monoflouride c) iodine monochloride
For the reaction Br2 (g) + Cl2 (g) → 2 BrCl Kp = 1.11 x 10-4...
For the reaction Br2 (g) + Cl2 (g) → 2 BrCl Kp = 1.11 x 10-4 at 150K. a) If 1.0 atm each of bromine and chlorine gas are placed in an otherwise empty 1 L container and allowed to equilibrate at a temperature of 150K, what will be the partial pressures at equilibrium of all three gases? Br2  atm Cl2  atm BrCl  atm b) suppose 0.2 atm each of all three gases are placed in a selaed container and allowed to equilibrate...
Chlorine gas reacts with fluorine gas to form chlorine trifluoride. Cl2 (g) + 3 F2 (g)...
Chlorine gas reacts with fluorine gas to form chlorine trifluoride. Cl2 (g) + 3 F2 (g) → 2 ClF3 (g) A 1.65 L reaction vessel, initially at 298 K, contains chlorine gas at a partial pressure of 337 mmHg and fluorine gas at a partial pressure of 741 mmHg . What is the pressure of ClF3 in the reaction vessel after the reaction? Enter your answer numerically, in terms of mmHg.
Carbon monoxide and chlorine gas react to form phosgene: CO(g)+Cl2(g)⇌COCl2(g) Kp = 3.10 at 700 K...
Carbon monoxide and chlorine gas react to form phosgene: CO(g)+Cl2(g)⇌COCl2(g) Kp = 3.10 at 700 K If a reaction mixture initially contains 345 torr of CO and 452 torr of Cl2, what is the mole fraction of COCl2 when equilibrium is reached? please be sure of your answer its my last attempt
QUESTION #1: Carbon monoxide and chlorine gas react to form phosgene: CO(g)+Cl2(g)⇌COCl2(g) Kp = 3.10 at...
QUESTION #1: Carbon monoxide and chlorine gas react to form phosgene: CO(g)+Cl2(g)⇌COCl2(g) Kp = 3.10 at 700 K If a reaction mixture initially contains 321 torr of CO and 157 torr of Cl2, what is the mole fraction of COCl2 when equilibrium is reached? QUESTION #2: Calculate the concentration of all species in a 0.150 M solution of H2CO3 [H2CO3], [HCO−3], [CO2−3], [H3O+], [OH−] = _____?_____ QUESTION #3: Write the formula for the conjugate base of each of the following...
Chlorine gas reacts with fluorine gas to form chlorine trifluoride. Cl2(g) + 3 F2(g) --> 2...
Chlorine gas reacts with fluorine gas to form chlorine trifluoride. Cl2(g) + 3 F2(g) --> 2 ClF3(g) A 2.00-L reaction vessel, initially at 298 K, contains chlorine gas at a partial pressure of 337 mmHg and fluorine gas at a partial pressure of 729 mmHg. Identify the limiting reactant and deter- mine the theoretical yield of ClF3 in grams. I got 4.84g ClF3 for this problem, but the textbook answer is 2.84g. Can anyone tell me where I went wrong,...
ADVERTISEMENT
ADVERTISEMENT
ADVERTISEMENT