In: Chemistry
1) Any species which dissociates in water to give Hydroxyl (OH-) ion and counter cation produce a basic solution.
The general formual for such a salt is Mx(OH)y.Which dissociates as,
Mx(OH)y ----------> xM+ + yOH- .
e.g. NaOH, KOH, Ba(OH)2 etc.
2) The salt of weak acid and strong base also on dissolution in water produces solution with basic of alkaline pH (pH>7)
Dissolution of salt in water is termed as hydrolysis of salt.
Hydrolysis of salt of weak acid and strong base is represented as,
BA + H2O <------------> BOH + HA
Salt Base (strong) Acid (weak)
BOH being strong base ionizes in water completely as, BOH -------> B+ + OH- .
and HA being weak acid ionizes only slightly in water as, AH <----------> A- + H+ .
Hence there is far greater concentration of OH- ions than H+ ions which produces basicity in the solution formed.
e.g. Sodium acetate (CH3COO-Na+) salt. It is a salt of weak organic acid (CH3COOH acetic acid) and strong base (NaOH). I.e. a salt of weak acid and strong base. Hence aqueous solution of sodium acetate will form solution with basic pH (pH>7).