In: Chemistry
Five moles of monatomic ideal gas are contained at a pressure of 4 atm and a temperature of 250 K. 35400 J of heat are transferred to the gas. Then, the gas pressure is used to expand a piston, and the expanding gas does 1200 J of work against its surroundings. However, the piston is not perfectly insulated, and 600 J of heat is lost from the gas during the expansion. All processes are reversible. Calculate the final temperature of the gas.
Moles of Gas = 5
Pressure = 4 atmosphere
Temperature = 250 K
Q = 35400 J
The work done by the gas = 1200J
Heat loss = 600 J
a) Initial temperature = 250 K
b) Heat given = 35400
Let us calcualte the temperature at this point
QAB = n CV
T = 35400
(n) ((3/2) R) (
T) = 35400
J
(5 mole) ((3/2) 8.31 J/mole-K)
(
T) = 35400
J
( 62.35 J / K )
T = 35400
J
T = (500/12.5)
K
T = 567.76
New temperature =250 K + 567.76 K = 817.75 K
c) For final temperature
Heat total = -600 J = n CP
T
- 600 J = (5) ((5/2) R) (
T)
- 600 J = (5 ((5/2) 8.31 J/mole-K)
(
T)
-
T = - 5.77
K
Final tempeature = 817.75 - 5.77 = 811.9 K