In: Chemistry
compare your experimental value for the heat of fusion of ice with the accepted value , 6.01 kJ/mol. Comment on the comparison, and try to explain your error ( if it exists). How would you change your procedure to improve its accuracy ?
Heat of fuson is the amount of heat required to convert solid ice into liquid ice. Known quantiy of ice is melted by placing known volume of hot water in a platic container ( Acts like an insulator). The temperature rise of the system can be determined and latent heat of ice can be calculated by
Heat lost by hot water to reach a given final temperatue (T2) from initial temperature (T1) is given by
Mass of water* specific heat of water* (T2-T1) = Heat of fusion* mass of solid ice that is melted ( Heat absorbed by ice)
Volume of solid that is melted= final volume of water- initial volume of water
Mass of solid that is metled= volume of water ( that came from melting)* density
Latent heat of fusion = heat absorbed by water/ mass of ice.
The error exists in the density of the water that is normally assumed to be 1 g/cc. One way to overcome this problem is to measure the density of the sample by dividing the mass of water/ volume of water. Normally density is nor measured and hence density measurement is included in the procedure, we can imrprove the value of latent heat of fusion.