Part A
A certain first-order reaction has a rate constant of 2.30×10−2
s−1 at 25 ∘C. What is the value of k at 63 ∘C if Ea = 74.0 kJ/mol
?
Part B
Another first-order reaction also has a rate constant of
2.30×10−2 s−1 at 25 ∘C . What is the value of k
at 63 ∘C if Ea = 128 kJ/mol ?
If a 1st order reaction has a rate constant of 2.30 s^-1 at 25
degree C, and at a frequency factor of 2.51*10^5, calculate the
activation energy.
A) 9715 J/mol
B)186 J/mol
C) -186 J/mol
D) 2.51*10^4 J/mol
E) 2.51*10^-4 J/mol
a) At 25 °C the first-order rate constant for a reaction is 2.0
x 103 s-1. The activation energy is 15.0 kJ/mol. What is the value
of the rate constant at 75 °C? (5 pts).
b)A first-order reaction has rate constants of 4.6 x 10-2 s-1
and 8.1 x 10-2 s-1 at 0 °C and 20 °C, respectively. What is the
value of the activation energy? (5 pts)
An uncatalyzed reaction has a rate of 4.4 x 10-7 s–1 at room
temperature (25 °C). When an enzyme is added the rate is 3.3 x 104
s–1. If the height of the activation barrier for the uncatalyzed
rate is 28 kcal/mol, what is the height of the activation barrier
for the catalyzed rate? Report your answer in terms of kcal/mol to
the nearest tenths. Also, assume the pre-exponential terms for the
uncatalyzed and catalyzed reactions are the same.
22. The rate constant for a reaction is 4.62 x 10-3 s -1 at
300°C. The activation energy for the reaction is 46 kJ/mol. What is
the rate constant at 600°C?
A. 1.28 x 10-1 s -1
<-Answer
B. 4.66 x 101 s -1
C. 9.37 x 10-1 s -1
D. 4.72 x 103 s -1
E. 9.37 x 103 s -1
Please explain the process in many details.
A reaction has a rate constant of 1.22*10^-4/s at 27
0C and 0.230/s at 78 0C. Determine the
activation barrier for the reaction. What is the value of the rate
constant at 18 0C?
a. A certain first-order reaction (A→products) has a rate
constant of 3.00×10−3 s−1 at 45 ∘C. How many minutes does it take
for the concentration of the reactant, [A], to drop to 6.25% of the
original concentration?
b. A certain second-order reaction (B→products) has a rate
constant of 1.85×10−3M−1⋅s−1 at 27 ∘C and an
initial half-life of 300 s . What is the concentration of the
reactant B after one half-life?
A certain first-order reaction has a rate constant of
3.00×10−2 s−1s−1 at 21 ∘C∘C. What is the value of kk at
51 ∘C∘C if EaEaE_1 = 76.0 kJ/molkJ/mol ?
Express your answer using two significant figures.
Another first-order reaction also has a rate constant of
3.00×10−2 s−1s−1 at 21 ∘C∘C. What is the value of kk at
51 ∘C∘C if EaEaE_2 = 110 kJ/molkJ/mol ?
Express your answer using two significant figures.