In: Chemistry
Calculate pH Using Kw= 1.00X 10^-14 of 0.010 M HCl
Calculate pH Using Ka = 1.75 x 10^-5 of 0.010 M HC2H3O2
Calculate pH 0.0010 M NaOH
Calculate pH Using Kb= 1.77x 10 ^-5 of 0.010 M NH3
Calculate pH Using Ka = 1.75 x 10 ^-5 of 0.010 M NaC2H3O2
Calculate pH Using Kb = 1.77 x 10 ^-5 of 0.010 M NH4Cl
Answer : Here u have to acually first write the balanced equation and then by using ICE method you can solve it easily
1] Calculate pH Using Kw= 1.00X 10^-14 of 0.010 M HCl
here HCl ------------------------------- > H+ + Cl -
Hcl is trong acid will completely dissociate and hence we get H+ concentrtion = 0.010M
Ph = -Log[0.010] = 2
Hence the PH is = 2
2] Calculate pH Using Ka = 1.75 x 10^-5 of 0.010 M HC2H3O2
in case of monotropic we get
Ka = [X]2/ 0.010 -X = 1.75 * 10-5
neglecting X we get 0.010-X = 0.010
X 2 = 0.175 * 10-6
X = 0.418 * 10-3M
Hence concentration of H+ = 0.418 * 10-3
Ph = - log [ 0.418 * 10-3] = 2.62
Hence Ph = 2.62
3] Calculate pH 0.0010 M NaOH
POH = -log [ 0.0010] = 3
and we know that PH + POH = 14
Hence PH = 14-3 = 11
Hence the Ph value is 11
4] Calculate pH Using Kb= 1.77x 10 ^-5 of 0.010 M NH3
Here NH3 is stong base and hence POH = -Log [ 0.010] = 2
And Hence PH = 14 - 2 = 12
5} Calculate pH Using Ka = 1.75 x 10 ^-5 of 0.010 M NaC2H3O2
If it is mono basic. Now Kb = 10-14 /1.75 * 10-5 = 0.57 * 10-9
Kb = X2/ 0.010 = 0.57 * 10-9
X2 = 0.057 * 10-10
X = 0.238 * 10-5 M
POH = -log 0.238 * 10-5 = 4.37
Ph = 14-4.37 = 9.63
Hence PH = 9.63
5] Calculate pH Using Kb = 1.77 x 10 ^-5 of 0.010 M NH4Cl
Kb = X2 / 0.010 = 1.77 * 10-5
X2 = 0.177 * 10-6
X = 0.42 * 10-3
poh = - log [ 0.42 * 10-3] = 2.62
Ph = 11.38
Hecne this is all about the questions