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In: Chemistry

Calculate the concentration and the pH in a .10 M solution of sodium acetate, Na(CH3CO2). Equilibrium...

Calculate the concentration and the pH in a .10 M solution of sodium acetate, Na(CH3CO2). Equilibrium constant of acetic is 1.8*10^-5.

Solutions

Expert Solution

The dissociation of 0.10 sodium acetate CH3COONa yields 0.10 M acetate ion and 0.10 M Na+ ion.

                   CH3COO- (aq) + H2O (l) <------------> CH3COOH (aq) + OH- (aq)

I(M)             0.10                  -                               0                    0

C                 -x                                                    +x                  +x

Eq             (0.10-x)                                               x                   x

                         Kb = Kw/Ka = 5.55*10-10 = (x)(x) / (0.10-x)

By solving - x = [OH-] = 7.453*10-6 M

Thus - pOH = -log [OH-] = -log (7.453*10-6 ) = 5.12

Hence - pH = 14 - 5.12 = 8.88


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