What are the differences between the mechanism of free radical and coordination polymerization?

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Amanda K answered 6 months ago

Compare and contrast the key characteristics of anionic polymerization and conventional free-radical polymerization

Styrene is polymerized by free radical mechanism in solution. The initial monomer and initiator concentrations are...

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With the aid of diagrams describe the radical polymerization of vinyl acetate using AIBN as initiator....

With the aid of diagrams describe the radical polymerization of vinyl acetate using AIBN as initiator. Describe initiator formation, monomer initiation, and propagation steps. In addition, describe the various mechanisms by which chain termination (no capacity for further growth) can occur. Describe the various ways in which charge transfer could occur (potential for further growth) for the polymerization described in part (b) above.

Please explain the affects that concentration of monomer can have on typical a radical polymerization

Show mechanism for 2 methylpropane free radical monobromination. Explain why pryon undergoes substitute reaction like benzene...

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The living character of living radical polymerization is limited under certain conditions, such as high monomer...

The living character of living radical polymerization is limited under certain conditions, such as high monomer conversion, high initiator concentration, and high targeted molecular weight (>100,000). Explain why these conditions result in broadening of PDI and some difficulty in producing block copolymers with well-defined block lengths of different monomers.

Describe why termination in radical polymerization by disproportionation and combination result in different polydispersities. Which results...

Describe why termination in radical polymerization by disproportionation and combination result in different polydispersities. Which results in a higher PDI?

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What are the differences between the mechanism of free radical and coordination polymerization?

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