Question

In: Chemistry

Calculate the pH of the following dilute solutions: (a) 3.42x10-8 M hydroiodic acid, HI. (b) 5.77x10-9...

Calculate the pH of the following dilute solutions:

(a) 3.42x10-8 M hydroiodic acid, HI.

(b) 5.77x10-9 M KOH.

Solutions

Expert Solution

(a) 3.42x10-8 M hydroiodic acid, HI.

[H+]HI = 3.42x10-8

[H+]H2O = 1.0 x10-7

[H+]net = [H+]HI +[H+]H2O = 3.42x10-8 +1.0 x10-7

[H+]net = 1.34 x10-7

pH= -log[H+]= -log(1.34 x10-7) =6.87

      pH=    6.87

(b) 5.77x10-9 M KOH.

[OH-]KOH = 5.77x10-9

[OH-]H2O = 1.0 x10-7

[OH-]net = [OH-]KOH + [OH-]H2O

                          =5.77x10-9 +1.0 x10-7

                    = 1.0577 x 10-7

pOH= -log [OH-]

        = -log(1.0577 x 10-7)

          = 6.97

pH= 14 -pOH

    pH= 7.03

                      


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