Solution:
Raw materials: Glue
manufacturers obtain bones and tissues of animals from
slaughterhouses, tanneries, and meat packing companies; it is no
coincidence that the world's largest glue manufacturer is the dairy
called Borden Company. The animal remains that are the raw
materials for glue may include ears, tails, scraps of hide or skin,
scrapings from the fleshy sides of hides, tendons, bones, and feet.
Similarly, manufacturers of fish glue obtain bones, heads, scales,
and skins of fish from canneries and other processing plant.
Process description:
- With only minor variations, the same basic processes are used
to make bone glue, hide or skin glue, and fish glue. The hides and
other scraps are washed so that dirt is removed, and they are
soaked to soften them. This material is called stock, and it is
passed through a series of water baths in which more and more lime
is added to make the hides and skins swell and break them down. The
swollen hides are rinsed in a large washing machine to remove the
lime. The last traces of lime are eliminated by treating the stock
with weak acids like acetic or hydrochloric acid. Finally, the
stock is cooked either by boiling, it in open tanks or cooking it
under pressure in autoclaves.
- Cooking at the correct temperature and for the right length of
time breaks down the collagen and converts it into glue. If the
temperature or timing is off, the quality of the glue will be
ruined. Large steam coils in the open tanks heat the water and
product to 160°F (70°C). Three or four treatments with clean water
are performed at increasing temperatures (or pressures if a
pressurized system is used). The resulting liquid, called "glue
liquor" is extracted and reheated again to thicken the glue.
- When cooled, this material looks like jelly and is solid;
although it looks like the kind of gelatin used in food, it
contains impurities. To remove the impurities and make the glue
clear, chemicals like alum or acid followed by egg albumin may be
added. These chemicals cause the impurities to precipitate, or fall
out, of the glue. Mechanical methods can also be used to clean the
glue. These include passing the glue through a series of mechanical
filters or through paper filters or ground bone called bone
char.
- Different additives are mixed with the glue liquor to make
brown, clear, or white glue. Sulfurous acid, phosphoric acid, or
alum are among these additives. Zinc oxide is added to produce
white "school glue."
- To this point, the glue is a weak, runny liquid. It is made
more concentrated in vacuum evaporators and dried in one of several
methods. The glue can be chilled into either sheets or blocks then
suspended on nets to dry and become still more concentrated. The
glue can also be dropped as beads or "pearls" into a non-water
bearing liquor that further dries the concentrated beads. The
pearls, blocks, or sheets are then mixed to the right consistency
and pumped into bottles or jars for sale.
Process flow sheet :
Engineering problem :
1. Volatility in raw materials
2. Raw material supply
3. An important challenge facing adhesive manufacturers and
users is the replacement of adhesive systems based on organic
solvents with systems based on water.
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