Question

In: Chemistry

Ethanol boils at 73.30 degrees Celsius at atmospheric pressure. The heat of vaporization, ΔΗvapis 39.3 kJ/mol....

Ethanol boils at 73.30 degrees Celsius at atmospheric pressure. The heat of vaporization, ΔΗvapis 39.3 kJ/mol. The melting point at atmospheric pressure is -114.10 degrees Celsius. The triple point is at pressure 0.00043 Pa and temperature -123.00 degrees Celsius. The density of liquid Ethanol at 25.0 degrees Celsius is 0.783 gr/cm3.

  1. What is the vapor pressure of liquid ethanol at 30.00 degrees Celsius?
  2. The heat of fusionΔΗmeltis 4.9 kJ/mol. Calculate the change in volume brought about by a transition from the liquid phase to the solid phase at 300 K. Assume that the coexistence curve solid-liquid is a straight line with a constant slope along its entire trajectory. Is the result logical?
  3. Draw the phase diagram, including the points referred to in the question.

Solutions

Expert Solution

a) As per phase diagram of ethanol shown below, the vapour pressure of liquid ethanol at 30 Degree Celsius is 0 bara; as there is no vapours of ethanol formed at the given temperature.


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