In: Chemistry
In the third century B.C., the Greek mathematician Archimedes is said to have discovered an important principle that is useful in density determinations. The story told is that King Hiero of Syracuse (in Sicily) asked Archimedes to verify that an ornate crown made for him by a goldsmith consisted of pure gold and not a gold–silver alloy. Archimedes had to do this, of course, without damaging the crown in any way. Describe how Archimedes did this, or if you don’t know the rest of the story, rediscover Archimedes’s principle and explain how it can be used to settle the question.
After sitting in a bathtub that was nearly full and observing the water splashing over the side, Archimedes realized that the crown—when submerged in water—would displace a volume of water equal to its volume. Once Archimedes determined the volume in this way and determined the mass of the crown with a balance, he was able to calculate the crown’s density. Since the gold-silver alloy has a different density (it is lower) than pure gold, Archimedes could tell that the crown was not pure gold.
Archimedes discovered displacement principle: crown in water displaces equal volume, aiding in density calculation.