Question

how can we determin the violation of NAAQS of a spesific data given ?

Answer 1

The National Ambient Air Quality Standards (NAAQS) basically sets a guideline for six primary air quality pollutants and how much they can measure. So for the given air quality sample, we need to do tests and see how the results are

If any of the thresholds are not met or exceeded, then the sample has violated the NAAQS test.

Pollutant	Primary or Secondary	Averaging Time	Level	Form
Carbon Monoxide	primary	8 hours	9 ppm	Not to be exceeded more than once per year
1 hour	35ppm
Lead	primary and	Rolling 3 month average	.15 μg/m3	Not to be exceeded
secondary
Nitrogen Dioxide	primary	1 hour	100 ppb	98th percentile of 1-hour daily maximum concentrations, averaged over 3 years
primary and	1 year	53 ppb	Annual Mean
secondary	0.07 ppb
Ozone	primary and	8 hours	0.07ppm	Annual fourth-highest daily maximum 8-hour concentration, averaged over 3 years
secondary
Particule Pollution (PM)	primary	1 year	12.0 μg/m3	annual mean, averaged over 3 years
secondary	1 year	15.0 μg/m3	annual mean, averaged over 3 years
primary and	24 hours	35 μg/m3	98th percentile, averaged over 3 years
secondary
primary and	24 hours	150 μg/m3	Not to be exceeded more than once per year on average over 3 years
secondary
Sulphur Dioxide	primary	1 hour	75 ppb	99th percentile of 1-hour daily maximum concentrations, averaged over 3 years
secondary	3 hours	0.5 ppm	Not to be exceeded more than once per year

So test the sample for 8 hours at different times of the year, or for 1 hour, or for 24hours depending on the table above and check if any violations.