In: Chemistry
Question 1.
An environmental scientist isolates a pollutant (compound X)
from a factory’s effluent stream and...
Question 1.
An environmental scientist isolates a pollutant (compound X)
from a factory’s effluent stream and dissolves it in water.
Experiments are then conducted using liquid – liquid extraction to
optimize its extraction. Using diethyl ether as the extracting
phase, the following distribution ratios, D, are calculated as a
function of pH:
pH
|
2
|
4
|
6
|
8
|
10
|
12
|
D
|
0.008
|
0.8
|
39
|
76
|
75
|
76
|
- Does compound X appear to have acidic functional groups, basic
functional groups or both types of groups? Explain your
answer.
- The distribution coefficient, KD, at pH 12 is 76.3.
Calculate the Ka value for compound X.
- The scientist performed multiple extractions of the pollutant
from 10 mL of water at pH 6 using a total volume of diethyl ether
of 100 mL. What mass of compound X will remain in the aqueous phase
after 4 consecutive extractions if the initial
concentration of the pollutant was 0.1 M.
(Note: molar mass of compound X = 76
g/mol)