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In: Chemistry

Question 1. An environmental scientist isolates a pollutant (compound X) from a factory’s effluent stream and...

Question 1.

An environmental scientist isolates a pollutant (compound X) from a factory’s effluent stream and dissolves it in water. Experiments are then conducted using liquid – liquid extraction to optimize its extraction. Using diethyl ether as the extracting phase, the following distribution ratios, D, are calculated as a function of pH:

pH

2

4

6

8

10

12

D

0.008

0.8

39

76

75

76

  1. Does compound X appear to have acidic functional groups, basic functional groups or both types of groups? Explain your answer.
  2. The distribution coefficient, KD, at pH 12 is 76.3. Calculate the Ka value for compound X.
  3. The scientist performed multiple extractions of the pollutant from 10 mL of water at pH 6 using a total volume of diethyl ether of 100 mL. What mass of compound X will remain in the aqueous phase after 4 consecutive   extractions if the initial concentration of the pollutant was 0.1 M.

(Note: molar mass of compound X = 76 g/mol)

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