- When a solid or a liquid evaporates to a gas in a closed
container, the molecules cannot escape.
- Some of the gas molecules will eventually strike the condensed
phase and condense back into it.
- When the rate of condensation of the gas becomes equal to the
rate of evaporation of the liquid or solid, the amount of gas,
liquid and/or solid no longer changes.
- The gas in the container is in
equilibrium with the liquid or
solid.
- The pressure exerted by the gas in equilibrium with a solid or
liquid in a closed container at a given temperature is called the
vapor pressure.
- The vapor pressure of a liquid varies with its temperature.As
the temperature of a liquid or solid increases its vapor pressure
also increases. Conversely, vapor pressure decreases as the
temperature decreases.
Hydrogen bonding exist within water molecules. This hydrogen
bonding raises the vapor pressure of water. Hence, we can say that
water has high vapor pressure.