Question

In: Chemistry

a. Sketch a cooling curve as you go from a gas to a solid for a...

a. Sketch a cooling curve as you go from a gas to a solid for a pure substance.

b. Label each segment.

c. Explain the regions.

d. Why are there slope changes in your curve?

e. Describe what is happening on a cooling curve when you have a level, horizontal line (no change in temperature over time).

Solutions

Expert Solution

The initial point of the graph is the starting temperature of the matter, here noted as the "pouring temperature". When the phase change occurs there is a "thermal arrest", that is the temperature stays constant. This is because the matter has more internal energy as a liquid or gas than in the state that it is cooling to. The amount of energy required for a phase change is known as latent heat. The "cooling rate" is the slope of the cooling curve at any point.

In the part of the curve where the temperature decreases, the kinetic energy also decreases while the potential energy stays the same. However, at the phase transition, where the curve is flat, the kinetic energy stays the same while the potential energy decreases


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