The entropy of mixing typically is the major energetic
contributor leading to solvation of polymer. as...
The entropy of mixing typically is the major energetic
contributor leading to solvation of polymer. as the molecular
weight of polymer increases, the entropic term playes a diminishing
role, Expline using the Flory Huggins equation?
Calculate (a) the (molar) Gibbs energy of mixing, (b) the (molar) entropy of mixing when the two major components of air (nitrogen and oxygen) are mixed to form air. The mole fractions of N2 and O2 are 0.78 and 0.22, respectively. Is the mixing spontaneous?
snowboards are typically made out of a thermosetting
polymer (i.e. a three dimensionally connected glassy polymer). what
type of mechanical behavior would you expect from that type of
polymer and why do you suppose reinforcing the polymer with fiber
would alleviate problems that might occur due to the mechanical
behavior of the polymer?
14.) Carbon dioxide, which is recognized as the major
contributor to global warming as a "greenhouse gas," is formed when
fossil fuels are combusted, as in electrical power plants fueled by
coal, oil, or natural gas. One potential way to reduce the amount
of CO2 added to the atmosphere is to store it as a compressed gas
in underground formations. Consider a 1000-megawatt coal-fired
power plant that produces about 7×106 tons of CO2 per
year.
1 ton = 907.185 kg...
6. Air pollution problem. Consider an airshed in which there is
one major contributor to air pollution--a cement-manufacturing
plant whose annual production capacity is 2.500,000 barrels of
cement. Figures are not available to determine whether the plant
has been operating at capacity. Although the kilns are equipped
with mechanical collectors for air pollution control, the plant
still emits 2.0 lb of dust per barrel of cement produced. There are
two types of electrostatic precipitators that can be installed to
control...
Constants | Periodic Table
Carbon dioxide, which is recognized as the major contributor to
global warming as a "greenhouse gas," is formed when fossil fuels
are combusted, as in electrical power plants fueled by coal, oil,
or natural gas. One potential way to reduce the amount of CO2 added
to the atmosphere is to store it as a compressed gas in underground
formations. Consider a 1000-megawatt coal-fired power plant that
produces about 5×106 tons of CO2 per year.
Part A...
A stretched-out polymer has lower entropy than a contracted one
(think back to the rubber band problem). Applying mechanical forces
to a polymer stretches it out, and it is also more likely to react
by breaking bonds along the polymer chain (compared to the
contracted case). a. Draw the reaction energy profile for the
zero-force and mechanically biased cases. b. Use the Arrhenius
expression to explain why the mechanochemical bond breaking is
faster
Answer and explain:
5. True or False: The entropy of mixing perfect gases is always
positive.
6. True or False: The chemical potential of pure liquid water at
standard conditions is higher than the standard chemical potential
of liquid water in an aqueous solution
Problem 1.
Derive an expression for the mixing entropy ∆Smix of a ternary
system.
Simplify your result, writing it as the total number of
particles N times a purely intensive function of the mole fractions
of all three components.
Calculate the enthalpy, entropy, and Gibbs free energy of mixing
when 1.00 mol hexane is mixed with 1.00 mol heptane at 298 K. You
may treat this solution as ideal. Sketch the plot of entropy of
mixing vs. mole fraction, and then sketch another plot for entropy
vs. mass fraction. Calculate the mass fractions of hexane and
heptane that would provide the greatest entropy of mixing.
The lab name is Electrochemical Determination of entropy of
mixing
Explain briefly why complementary solutions were used in this
experiment. How does this experimental design effectively simulate
the hypothetical reversible mixing process discussed earlier in the
notes( earlier in the notes I put reversible happen infinitesimally
slow)? What is wrong with measuring the voltage of a cell
containing only one solute component on each side (i.e., Fe(II) of
a given molality on one side and Fe(III) with the same molality...