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In: Chemistry

Calculate the [H+], [OH-], pH, pOH for the resulting solution if 20.00 mL sample of 0.2650...

Calculate the [H+], [OH-], pH, pOH for the resulting solution if 20.00 mL sample of 0.2650 M NaOH was titrated with 21.33 mL of 0.1175 M H2SO4.

Solutions

Expert Solution

    H2SO4                                                                  NaOH

MA   = 0.1175M                                                      MB = 0.2650M

VA    = 21.33ml                                                         VB   = 20ml

           M    =     MBVB-MAVA/VA + VB

                  =    0.2650*20-0.1175*21.33/21.33+20

                  = 2.793725/41.33   = 0.0676M

      M    = [OH^-]   = 0.0676M

      [H^+]    = Kw/[OH^-]

                 = 1*10^-14/(0.0676)    = 1.48*10^-13M

       POH   = -log[OH^-]

                 = -log0.0676

                 = 1.17

         PH = 14-POH

                 = 14-1.17   = 12.83


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