Question

In: Chemistry

Give examples from the literature of metal complexes with coordination numbers (CN) of 2, 3, 4,...

Give examples from the literature of metal complexes with coordination numbers (CN) of 2, 3, 4, 5, 6, 7 and 8 (formula, structure). What is the highest Coordination Number found for a metal ion?

Solutions

Expert Solution

Answer:

Coordination number                           Example

      2                                                  [Ag(NH3)2]+

      3                                                  [Cu(CN)3]2-

      4                                                  [Ni(CO)4]

      5                                                  [Co(Cl)5]2-

      6                                                  [Co(Cl)6]3-

      7                                                  [Zr(F)7]3-

      8                                                  [ReF8]2-

      9                                                  [ReH9]2-

Highest possible coordination number is 16.


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