Question

In: Chemistry

What is the half-life (T1/2) of a radioactive element with the following conditions? -Initial Activity =...

What is the half-life (T1/2) of a radioactive element with the following conditions?

-Initial Activity = 1000 milliCuries

-Final Activity = 400 milliCuries

-Elapsed Time= 20.0 days

Solutions

Expert Solution

All radio active elements undergo first order reactions

For a first order reaction rate constant , k = ( 2.303 /t )x log ( Ao / A)

Where

Ao = initial activity = 1000 mC

A = final activity = 400 mC

t = time = 20.0 days

             = 20.0x24x60x60 s

            = 1728000 s

Plug the values we get

k = ( 2.303 /t )x log ( Ao / A)

k = ( 2.303 /1728000 )x log ( 1000/400 )

= 5.30x10-7 s-1

Half-life of first order reaction , t1/2 = 0.693/k

                                                      = 0.693 / (5.30x10-7 )

                                                      = 1.307x106 s

                                                      = 1.307x106 /(60x60x24) days

                                                      = 15.1 days

Therefore the half life is 15.1 days


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