Question

In: Chemistry

Before 1961, the standard for atomic masses was the isotope 16O, to which physicists assigned a

Before 1961, the standard for atomic masses was the isotope 16O, to which physicists assigned a value of exactly 16. At the same time, chemists assigned a value of exactly 16 to the naturally occurring mixture of the isotopes 16O, 17O, and 18O. Would you expect atomic masses listed in a 60-year-old text to be the same, generally higher, or generally lower than in this text? Explain.

Solutions

Expert Solution

In a 60-year-old chemistry textbook, the atomic mass for oxygen would be exactly 16 u because chemists assigned precisely 16 u as the atomic mass of the naturally occurring mixture of oxygen isotopes. This value is slightly higher than the value of 15.9994 in modern chemistry textbooks. Thus, we would expect all other atomic masses to be slightly higher as well in the older textbooks.


Older chemistry textbooks list oxygen's atomic mass as precisely 16 u, higher than modern 15.9994 u. Other masses similarly adjusted.

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