3.- ENTROPY EXERCISES.
From the absolute entropy values calculate the standard entropy
changes (ΔS °) of the following reactions at 25 C
a.- CaCO3(s) →→→ CaO (s) + CO2(g)
b.- N2(g) + 3H2(g) →→→ 2NH3(g)
c.- H2(g) + Cl2(g) →→→ 2HCl (g)
TABLE OF VALUES OF STANDARD ENTROPY (S °):
|
COMPOUND |
Standard Entropy (S°): J/ K-mol |
|
CaCO3(s) |
92.9 |
|
CaO (s) |
39.8 |
|
CO2(g) |
213.6 |
|
N2(g) |
192 |
|
H2(g) |
131 |
|
NH3(g) |
193 |
|
Cl2(g) |
223 |
|
HCl (g) |
187 |
In: Chemistry
1-Demonstrate how the spectral emissive power inside a blackbody
cavity changes with respect to the
following parameters:
a) Temperature and wavelength, hence, find E?(?, T), by:
(i) Creating a table with the (?, T) values as follows:
1. Wavelengths, ?, from 0.1 ?m to 100 ?m, on the first (left-most)
column. Use increments
of:
? 0.1 ?m from 0.1 ?m to 1.0 ?m;
? 0.5 ?m from 1.0 ?m to 10 ?m;
? 1.0 ?m from 10 ?m to 100 ?m;
2. Temperatures, T, values of: 273.15 K; 773.15 K; 1273.15 K;
1773.15 K; 2273.15 K; 5000
K; and, 10000 K.
3. Calculate E?(?, T) using units of W/m2·?m and assume the
constants C1 = 374210000
and C2 = 14388.
Set up your table with each separate column corresponding to each
given value of T.
Ensure that you clearly label each column in your table and include
the relevant units.
[Hint: There should be seven separate columns in your table for the
E?(?, T) calculations
and eight columns in your table altogether with the inclusion of
the left-most column
consisting of the ? values.
The recommendation is that you fill in each separate column in your
table using a
different background colour in order to facilitate the examination
of the different T
calculations and to assist in identifying the corresponding
plots.]
4. Clearly demarcate the visible region in your table. You may do
this by selecting a
different coloured font for the values of ? (and the corresponding
E? values) that fall
within this region.
(ii) Plot the calculated values of E?(?, T) ensuring that you set
out each plot as follows:
1. Display the calculated E?(?, T) values on the vertical
axis.
2. Display the wavelengths on the horizontal axis. Select the
logarithmic scale, to base 10,
to display your values on this axis.
3. Clearly demarcate the visible region in each plot.
4. Include a title in each plot, clearly identifying the relevant
value of T and ensure that you
label both axes (including units).
[Hint: The recommendation is that you fill in the background of
each plot in the same
colour as the corresponding column in your table in order to
facilitate the analyses of
the different T calculations.]
In: Physics
The following problem has you examine the impact of interest rate changes on bank profits using basic gap analysis.
Assume that the amount of variable- and fixed-rate assets and liabilities is fixed over the next year. In other words, no assets or liabilities will mature during this period. For each part, be sure to give a numerical answer.
Suppose a bank has $70M in variable-rate assets and $120M in variable-rate liabilities. What is the impact on the bank’s profits of a 1.5% increase in interest rates?
If the bank has $200M in assets, what is the impact on the return on assets (ROA)?
If the bank has $200M in assets and an capital of $15M, what is the impact on the
return on equity (ROE)?
In: Accounting
Use the dynamic AD-AS model to explain circumstances by which productivity and technological changes can lead to an increase in unemployment. Discuss what happens to the price level depending on the assumptions you make.(please explain in detail)
In: Economics
1. what are the common age-related changes of
respiratory system in older adult?
2. In selected respiratory conditions: Give nursing management and
medication.
a. Chronic Obstructive Pulmonary Disease
b. Lung cancer
c. Pneumonia
3. What self-imposed and environmentally imposed risks to younger
adults can contribute to the development of respiratory conditions
in later life?
In: Nursing
A parcel of air moves adiabatically and without phase changes of water from 900 hPa (Point A) to 700 hPa (Point B) and then to 800 hPa (Point C).
(a) At which of these three points is the relative humidity the largest, and at which point is it the smallest? Justify your answer
(b) At which of these three points is the specific humidity the largest, and at which point is it the smallest? Justify your answer
In: Physics
Calculate the heat/mole KCl when KCl is dissolved in water if 3.00 grams of KCl changes the temperature of 301 mL of water from 23oC to 29oC. (swater = 4.184 J/goC)
In: Chemistry
What material changes could advance the item leading?
(for example, to improvements in sustainability, accessibility, affordability, equity, performance, etc..)
Use materials property data and knowledge of materials selection strategies to support your proposed material innovation.
(Can you please not answer handwriting)
In: Mechanical Engineering
Recent global changes in political and economic systems show that
Multiple Choice
the multipolar world dominated by a number of civilizations of the Cold War era has vanished and is now being replaced by abipolar world.
many undeveloped and impoverished national markets of eastern Europe, Latin America, Africa, and Asia are potentiallyenormous for international business.
a lack of deregulation was the cause for the global financial crisis of 2008–2009.
it is guaranteed that democracy will thrive in most of the world's newer democratic states.
East European communist ideology is now widespread.
In: Economics
Variations in the resistivity of blood can give valuable clues to changes in the blood's viscosity and other properties. The resistivity is measured by applying a small potential difference and measuring the current. Suppose a medical device attaches electrodes into a 1.5-mm-diameter vein at two points 5.0 apart.
What is the blood resistivity if a 8.9 V potential difference causes a 240 mu A current through the blood in the vein (in omega*m)?
In: Other